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Guest-shuttling in a nanosized metallobox
dc.contributor.author | Ibáñez, Susana | |
dc.contributor.author | Salvà, Paula | |
dc.contributor.author | Dawe, Louise N. | |
dc.contributor.author | Peris, Eduardo | |
dc.date.accessioned | 2024-01-29T12:55:35Z | |
dc.date.available | 2024-01-29T12:55:35Z | |
dc.date.issued | 2024-01-05 | |
dc.identifier.citation | Ibáñez, S., Salvà, P., Dawe, L. N., & Peris, E. V. (2024). Guest‐shuttling in a Nanosized Metallobox. Angewandte Chemie International Edition | ca_CA |
dc.identifier.issn | 1433-7851 | |
dc.identifier.issn | 1521-3773 | |
dc.identifier.uri | http://hdl.handle.net/10234/205563 | |
dc.description.abstract | An iridium-conjoined long and narrow metallorectangle was obtained by combining a quinoxalinophenanthrophenazine-connected Janus-di-imidazolylidene ligand and pyrazine. The size and shape of this assembly together with the fused polyaromatic nature of its panels provides it with properties that are uncommon for other metallosupramolecular assemblies. For example, this nanosized ‘slit-like’ metallobox is able show very large binding affinities with planar organic molecules in such a way, that the cavity is asymmetrically occupied by the guest molecule. This unsymmetrical conformation leads to the existence of a large amplitude motion of these guests, which slide between the two sides of the cavity of the host, thus constituting rare examples of molecular shuttles. | ca_CA |
dc.description.sponsorShip | Funding for open access charge: CRUE-Universitat Jaume I | |
dc.format.extent | 7 p. | ca_CA |
dc.format.mimetype | application/pdf | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | Wiley | ca_CA |
dc.relation.isPartOf | Angewandte Chemie International Edition (2024) | ca_CA |
dc.rights.uri | http://creativecommons.org/licenses/by-nc/4.0/ | ca_CA |
dc.subject | host-guest chemistry | ca_CA |
dc.subject | molecular shuttles | ca_CA |
dc.subject | N-heterocyclic carbenes | ca_CA |
dc.subject | polycyclic aromatic hydrocarbons | ca_CA |
dc.subject | supramolecular organometallic complexes | ca_CA |
dc.title | Guest-shuttling in a nanosized metallobox | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | https://doi.org/10.1002/anie.202318829 | |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | ca_CA |
dc.type.version | info:eu-repo/semantics/publishedVersion | ca_CA |
project.funder.name | Ministerio de Ciencia e Innovación | ca_CA |
project.funder.name | Generalitat Valenciana, Conselleria de Cultura, Educación y Ciencia | ca_CA |
project.funder.name | Universitat Jaume I | ca_CA |
oaire.awardNumber | PID2021-127862NB-I00 | ca_CA |
oaire.awardNumber | CIPROM/2021/079 | ca_CA |
oaire.awardNumber | UJI-B2020-01 | ca_CA |
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