Guest-shuttling in a nanosized metallobox
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Other documents of the author: Ibáñez, Susana; Salvà, Paula; Dawe, Louise N.; Peris, Eduardo
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comunitat-uji-handle2:10234/160292
comunitat-uji-handle3:10234/160293
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Title
Guest-shuttling in a nanosized metalloboxDate
2024-01-05Publisher
WileyISSN
1433-7851; 1521-3773Bibliographic citation
Ibáñez, S., Salvà, P., Dawe, L. N., & Peris, E. V. (2024). Guest‐shuttling in a Nanosized Metallobox. Angewandte Chemie International EditionType
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info:eu-repo/semantics/publishedVersionSubject
Abstract
An iridium-conjoined long and narrow metallorectangle was obtained by combining a quinoxalinophenanthrophenazine-connected Janus-di-imidazolylidene ligand and pyrazine. The size and shape of this assembly together ... [+]
An iridium-conjoined long and narrow metallorectangle was obtained by combining a quinoxalinophenanthrophenazine-connected Janus-di-imidazolylidene ligand and pyrazine. The size and shape of this assembly together with the fused polyaromatic nature of its panels provides it with properties that are uncommon for other metallosupramolecular assemblies. For example, this nanosized ‘slit-like’ metallobox is able show very large binding affinities with planar organic molecules in such a way, that the cavity is asymmetrically occupied by the guest molecule. This unsymmetrical conformation leads to the existence of a large amplitude motion of these guests, which slide between the two sides of the cavity of the host, thus constituting rare examples of molecular shuttles. [-]
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Angewandte Chemie International Edition (2024)Funder Name
Ministerio de Ciencia e Innovación | Generalitat Valenciana, Conselleria de Cultura, Educación y Ciencia | Universitat Jaume I
Project code
PID2021-127862NB-I00 | CIPROM/2021/079 | UJI-B2020-01
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info:eu-repo/semantics/openAccess
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