Guest-shuttling in a nanosized metallobox
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Otros documentos de la autoría: Ibáñez, Susana; Salvà, Paula; Dawe, Louise N.; Peris, Eduardo
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Mostrar el registro completo del ítemcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/160292
comunitat-uji-handle3:10234/160293
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Título
Guest-shuttling in a nanosized metalloboxFecha de publicación
2024-01-05Editor
WileyISSN
1433-7851; 1521-3773Cita bibliográfica
Ibáñez, S., Salvà, P., Dawe, L. N., & Peris, E. V. (2024). Guest‐shuttling in a Nanosized Metallobox. Angewandte Chemie International EditionTipo de documento
info:eu-repo/semantics/articleVersión
info:eu-repo/semantics/publishedVersionPalabras clave / Materias
Resumen
An iridium-conjoined long and narrow metallorectangle was obtained by combining a quinoxalinophenanthrophenazine-connected Janus-di-imidazolylidene ligand and pyrazine. The size and shape of this assembly together ... [+]
An iridium-conjoined long and narrow metallorectangle was obtained by combining a quinoxalinophenanthrophenazine-connected Janus-di-imidazolylidene ligand and pyrazine. The size and shape of this assembly together with the fused polyaromatic nature of its panels provides it with properties that are uncommon for other metallosupramolecular assemblies. For example, this nanosized ‘slit-like’ metallobox is able show very large binding affinities with planar organic molecules in such a way, that the cavity is asymmetrically occupied by the guest molecule. This unsymmetrical conformation leads to the existence of a large amplitude motion of these guests, which slide between the two sides of the cavity of the host, thus constituting rare examples of molecular shuttles. [-]
Publicado en
Angewandte Chemie International Edition (2024)Entidad financiadora
Ministerio de Ciencia e Innovación | Generalitat Valenciana, Conselleria de Cultura, Educación y Ciencia | Universitat Jaume I
Código del proyecto o subvención
PID2021-127862NB-I00 | CIPROM/2021/079 | UJI-B2020-01
Derechos de acceso
info:eu-repo/semantics/openAccess
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