Guest-shuttling in a nanosized metallobox
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Altres documents de l'autoria: Ibáñez, Susana; Salvà, Paula; Dawe, Louise N.; Peris, Eduardo
Metadades
Mostra el registre complet de l'elementcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/160292
comunitat-uji-handle3:10234/160293
comunitat-uji-handle4:
INVESTIGACIONMetadades
Títol
Guest-shuttling in a nanosized metalloboxData de publicació
2024-01-05Editor
WileyISSN
1433-7851; 1521-3773Cita bibliogràfica
Ibáñez, S., Salvà, P., Dawe, L. N., & Peris, E. V. (2024). Guest‐shuttling in a Nanosized Metallobox. Angewandte Chemie International EditionTipus de document
info:eu-repo/semantics/articleVersió
info:eu-repo/semantics/publishedVersionParaules clau / Matèries
Resum
An iridium-conjoined long and narrow metallorectangle was obtained by combining a quinoxalinophenanthrophenazine-connected Janus-di-imidazolylidene ligand and pyrazine. The size and shape of this assembly together ... [+]
An iridium-conjoined long and narrow metallorectangle was obtained by combining a quinoxalinophenanthrophenazine-connected Janus-di-imidazolylidene ligand and pyrazine. The size and shape of this assembly together with the fused polyaromatic nature of its panels provides it with properties that are uncommon for other metallosupramolecular assemblies. For example, this nanosized ‘slit-like’ metallobox is able show very large binding affinities with planar organic molecules in such a way, that the cavity is asymmetrically occupied by the guest molecule. This unsymmetrical conformation leads to the existence of a large amplitude motion of these guests, which slide between the two sides of the cavity of the host, thus constituting rare examples of molecular shuttles. [-]
Publicat a
Angewandte Chemie International Edition (2024)Entitat finançadora
Ministerio de Ciencia e Innovación | Generalitat Valenciana, Conselleria de Cultura, Educación y Ciencia | Universitat Jaume I
Codi del projecte o subvenció
PID2021-127862NB-I00 | CIPROM/2021/079 | UJI-B2020-01
Drets d'accés
info:eu-repo/semantics/openAccess
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