Radical Mechanism in the Elimination of 2-Arylsulfinyl Esters
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Otros documentos de la autoría: Latorre, Antonio; López Martín, Irakusne; Ramírez, Victoria; Rodríguez, Santiago; Izquierdo Ferrer, Javier; González, Florenci; Vicent Barrera, Cristian
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Título
Radical Mechanism in the Elimination of 2-Arylsulfinyl EstersAutoría
Fecha de publicación
2012-05Editor
American Chemical SocietyISSN
0022-3263; 1520-6904Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
http://pubs.acs.org/doi/abs/10.1021/jo300699wPalabras clave / Materias
Resumen
The mechanism of the dehydrosulfenylation of 2-arylsulfinyl esters was investigated. The reaction was found to follow a homolytic cleavage mechanism as verified by electrospray ionization tandem mass spectrometry and ... [+]
The mechanism of the dehydrosulfenylation of 2-arylsulfinyl esters was investigated. The reaction was found to follow a homolytic cleavage mechanism as verified by electrospray ionization tandem mass spectrometry and experimental work. Rearranged sulfoxides are obtained as byproduct during the elimination reaction. [-]
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The Journal of Organic Chemistry, 77, 11Derechos de acceso
This document is the unedited Author’s version of a Submitted Work that was subsequently accepted for publication in Journal of Organic Chemistry, copyright © American Chemical Society after peer review.
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info:eu-repo/semantics/openAccess
http://rightsstatements.org/vocab/InC/1.0/
info:eu-repo/semantics/openAccess
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