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Radical Mechanism in the Elimination of 2-Arylsulfinyl Esters

dc.contributor.authorLatorre, Antonio
dc.contributor.authorLópez Martín, Irakusne
dc.contributor.authorRamírez, Victoria
dc.contributor.authorRodríguez, Santiago
dc.contributor.authorIzquierdo Ferrer, Javier
dc.contributor.authorGonzález, Florenci
dc.contributor.authorVicent Barrera, Cristian
dc.date.accessioned2013-06-24T07:57:38Z
dc.date.available2013-06-24T07:57:38Z
dc.date.issued2012-05
dc.identifier.issn0022-3263
dc.identifier.issn1520-6904
dc.identifier.urihttp://hdl.handle.net/10234/67842
dc.description.abstractThe mechanism of the dehydrosulfenylation of 2-arylsulfinyl esters was investigated. The reaction was found to follow a homolytic cleavage mechanism as verified by electrospray ionization tandem mass spectrometry and experimental work. Rearranged sulfoxides are obtained as byproduct during the elimination reaction.ca_CA
dc.language.isoengca_CA
dc.publisherAmerican Chemical Societyca_CA
dc.relation.isPartOfThe Journal of Organic Chemistry, 77, 11ca_CA
dc.rightsThis document is the unedited Author’s version of a Submitted Work that was subsequently accepted for publication in Journal of Organic Chemistry, copyright © American Chemical Society after peer review.ca_CA
dc.rights.urihttp://rightsstatements.org/vocab/InC/1.0/*
dc.subjectElectrospray ionizationca_CA
dc.subjectElectrospray ionizationca_CA
dc.subjectRadical mechanismca_CA
dc.subjectMass spectrometryca_CA
dc.titleRadical Mechanism in the Elimination of 2-Arylsulfinyl Estersca_CA
dc.typeinfo:eu-repo/semantics/articleca_CA
dc.identifier.doihttp://dx.doi.org/10.1021/jo300699w
dc.rights.accessRightsinfo:eu-repo/semantics/openAccessca_CA
dc.relation.publisherVersionhttp://pubs.acs.org/doi/abs/10.1021/jo300699wca_CA


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