Radical Mechanism in the Elimination of 2-Arylsulfinyl Esters
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Títol
Radical Mechanism in the Elimination of 2-Arylsulfinyl EstersAutoria
Data de publicació
2012-05Editor
American Chemical SocietyISSN
0022-3263; 1520-6904Tipus de document
info:eu-repo/semantics/articleVersió de l'editorial
http://pubs.acs.org/doi/abs/10.1021/jo300699wParaules clau / Matèries
Resum
The mechanism of the dehydrosulfenylation of 2-arylsulfinyl esters was investigated. The reaction was found to follow a homolytic cleavage mechanism as verified by electrospray ionization tandem mass spectrometry and ... [+]
The mechanism of the dehydrosulfenylation of 2-arylsulfinyl esters was investigated. The reaction was found to follow a homolytic cleavage mechanism as verified by electrospray ionization tandem mass spectrometry and experimental work. Rearranged sulfoxides are obtained as byproduct during the elimination reaction. [-]
Publicat a
The Journal of Organic Chemistry, 77, 11Drets d'accés
This document is the unedited Author’s version of a Submitted Work that was subsequently accepted for publication in Journal of Organic Chemistry, copyright © American Chemical Society after peer review.
http://rightsstatements.org/vocab/InC/1.0/
info:eu-repo/semantics/openAccess
http://rightsstatements.org/vocab/InC/1.0/
info:eu-repo/semantics/openAccess
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