A New Approach to the Reduction of Carbon Dioxide: CO2 Reduction to Formate by Transfer Hydrogenation in iPrOH
comunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/7053
comunitat-uji-handle3:10234/8639
comunitat-uji-handle4:
INVESTIGACIONEste recurso está restringido
http://dx.doi.org/10.1021/om900820x |
Metadatos
Título
A New Approach to the Reduction of Carbon Dioxide: CO2 Reduction to Formate by Transfer Hydrogenation in iPrOHFecha de publicación
2010Editor
American Chemical SocietyISSN
0276-7333Cita bibliográfica
Organometallics (2010), 29, 1, p. 275-277Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
http://pubs.acs.org/doi/abs/10.1021%2Fom900820xResumen
A series of four Ir and Ru catalysts have been tested in the reduction of CO2 to formate in the presence of H2. The iridium catalysts containing the basic NHC ligands were the ones to show better catalytic activities, ... [+]
A series of four Ir and Ru catalysts have been tested in the reduction of CO2 to formate in the presence of H2. The iridium catalysts containing the basic NHC ligands were the ones to show better catalytic activities, achieving high TON values of up to 1800 TON. The unprecedented reduction of CO2 with iPrOH through a hydrogen transfer process is also described. TON values of up to 150 were obtained. Two other secondary alcohols, cyclohexanol and 1-phenylethanol, were also used as hydrogen sources for the reduction of carbon dioxide. [-]
Derechos de acceso
Copyright © 2009 American Chemical Society
http://rightsstatements.org/vocab/InC/1.0/
info:eu-repo/semantics/closedAccess
http://rightsstatements.org/vocab/InC/1.0/
info:eu-repo/semantics/closedAccess
Aparece en las colecciones
- QUIO_Articles [705]