Listar por autoría "77a46b73-e3d1-4eb1-970b-2036ee021842"
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A New Approach to the Reduction of Carbon Dioxide: CO2 Reduction to Formate by Transfer Hydrogenation in iPrOH
Sanz, Sergio; Benítez Gómez, Miriam; Peris, Eduardo American Chemical Society (2010)A series of four Ir and Ru catalysts have been tested in the reduction of CO2 to formate in the presence of H2. The iridium catalysts containing the basic NHC ligands were the ones to show better catalytic activities, ... -
Intramolecular oxidation of the alcohol functionalities in hydroxyalkyl-n-heterocyclic carbene complexes of iridium and rhodium
Benítez Gómez, Miriam; Mas, Elena; Mata Martínez, Jose A; Peris, Eduardo WILEY-VCH Verlag (2011-08-04)A series of hydroxyalkyl-functionalized imidazolium salts have been coordinated to Rh and Ir to afford the corresponding MCp*–(NHC) (Cp*=pentamethylcyclopentadienyl) complexes. The reactivity of the new complexes has been ...