A New Approach to the Reduction of Carbon Dioxide: CO2 Reduction to Formate by Transfer Hydrogenation in iPrOH

dc.contributor.author	Sanz, Sergio
dc.contributor.author	Benítez Gómez, Miriam
dc.contributor.author	Peris, Eduardo
dc.date.accessioned	2012-12-03T15:48:40Z
dc.date.available	2012-12-03T15:48:40Z
dc.date.issued	2010
dc.identifier.citation	Organometallics (2010), 29, 1, p. 275-277	ca_CA
dc.identifier.issn	0276-7333
dc.identifier.uri	http://hdl.handle.net/10234/52681
dc.description.abstract	A series of four Ir and Ru catalysts have been tested in the reduction of CO2 to formate in the presence of H2. The iridium catalysts containing the basic NHC ligands were the ones to show better catalytic activities, achieving high TON values of up to 1800 TON. The unprecedented reduction of CO2 with iPrOH through a hydrogen transfer process is also described. TON values of up to 150 were obtained. Two other secondary alcohols, cyclohexanol and 1-phenylethanol, were also used as hydrogen sources for the reduction of carbon dioxide.	ca_CA
dc.format.extent	3 p.	ca_CA
dc.language.iso	eng	ca_CA
dc.publisher	American Chemical Society	ca_CA
dc.rights	Copyright © 2009 American Chemical Society	ca_CA
dc.rights.uri	http://rightsstatements.org/vocab/InC/1.0/	*
dc.title	A New Approach to the Reduction of Carbon Dioxide: CO2 Reduction to Formate by Transfer Hydrogenation in iPrOH	ca_CA
dc.type	info:eu-repo/semantics/article	ca_CA
dc.identifier.doi	http://dx.doi.org/10.1021/om900820x
dc.rights.accessRights	info:eu-repo/semantics/closedAccess	ca_CA
dc.relation.publisherVersion	http://pubs.acs.org/doi/abs/10.1021%2Fom900820x	ca_CA

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