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Catalytic enantioselective epoxidation of nitroalkenes
dc.contributor.author | Vidal-Albalat, Andreu | |
dc.contributor.author | Świderek, Katarzyna | |
dc.contributor.author | Izquierdo Ferrer, Javier | |
dc.contributor.author | Rodríguez, Santiago | |
dc.contributor.author | Moliner, Vicent | |
dc.contributor.author | González, Florenci | |
dc.date.accessioned | 2017-06-27T09:30:23Z | |
dc.date.available | 2017-06-27T09:30:23Z | |
dc.date.issued | 2016 | |
dc.identifier.citation | VIDAL-ALBALAT, A., et al. Catalytic enantioselective epoxidation of nitroalkenes. Chemical Communications, 2016, vol. 52, no 65, p. 10060-10063. | ca_CA |
dc.identifier.issn | 1359-7345 | |
dc.identifier.issn | 1364-548X | |
dc.identifier.uri | http://hdl.handle.net/10234/168105 | |
dc.description.abstract | Nitroepoxides are potentially exploitable as synthons with vicinal electrophilic centers. Nevertheless, although advances have been made in the field, enantioselective epoxidation of nitroalkenes is still a challenging process. Herein we show a convenient procedure for the preparation of optically active nitroepoxides in high enantiomeric excess and high chemical yield. The kinetic data of the best catalyst have been examined using computational methods based on DFT calculations. Interestingly, the results demonstrate that the enantioselectivity of the epoxidation of nitroalkenes by this kind of catalyst is not only kinetically but also thermodynamically controlled. | ca_CA |
dc.description.sponsorShip | This work was partially supported by Spanish Ministerio de Economia y Competitividad (ref. CTQ2015-66223-C2-1-P), Generalitat Valenciana (PROMETEOII/2014/022), and the Polish Ministry of Science and Higher Education ("Iuventus Plus'' project 0478/IP3/2015/73, 2015-2016). A. V.-A. thanks Generalitat Valenciana for a PhD grant (VALi+D Program). We thank Serveis Centrals d'Instrumentacio Cientifica and the Servei d'Informatica of Universitat Jaume I for technical support and computational resources, respectively. | ca_CA |
dc.format.extent | 4 p. | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | Royal Society of Chemistry | ca_CA |
dc.relation.isPartOf | Chemical Communications, 2016, vol. 52, no 65 | ca_CA |
dc.rights.uri | http://rightsstatements.org/vocab/CNE/1.0/ | * |
dc.subject | nitroalkenes | ca_CA |
dc.subject | epoxidation | ca_CA |
dc.subject | nitroepoxides | ca_CA |
dc.title | Catalytic enantioselective epoxidation of nitroalkenes | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | http://dx.doi.org/10.1039/C6CC03539F | |
dc.rights.accessRights | info:eu-repo/semantics/restrictedAccess | ca_CA |
dc.relation.publisherVersion | http://pubs.rsc.org/-/content/articlehtml/2016/cc/c6cc03539f | ca_CA |
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