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dc.contributor.authorVidal-Albalat, Andreu
dc.contributor.authorŚwiderek, Katarzyna
dc.contributor.authorIzquierdo Ferrer, Javier
dc.contributor.authorRodríguez, Santiago
dc.contributor.authorMoliner, Vicent
dc.contributor.authorGonzález, Florenci
dc.date.accessioned2017-06-27T09:30:23Z
dc.date.available2017-06-27T09:30:23Z
dc.date.issued2016
dc.identifier.citationVIDAL-ALBALAT, A., et al. Catalytic enantioselective epoxidation of nitroalkenes. Chemical Communications, 2016, vol. 52, no 65, p. 10060-10063.ca_CA
dc.identifier.issn1359-7345
dc.identifier.issn1364-548X
dc.identifier.urihttp://hdl.handle.net/10234/168105
dc.description.abstractNitroepoxides are potentially exploitable as synthons with vicinal electrophilic centers. Nevertheless, although advances have been made in the field, enantioselective epoxidation of nitroalkenes is still a challenging process. Herein we show a convenient procedure for the preparation of optically active nitroepoxides in high enantiomeric excess and high chemical yield. The kinetic data of the best catalyst have been examined using computational methods based on DFT calculations. Interestingly, the results demonstrate that the enantioselectivity of the epoxidation of nitroalkenes by this kind of catalyst is not only kinetically but also thermodynamically controlled.ca_CA
dc.description.sponsorShipThis work was partially supported by Spanish Ministerio de Economia y Competitividad (ref. CTQ2015-66223-C2-1-P), Generalitat Valenciana (PROMETEOII/2014/022), and the Polish Ministry of Science and Higher Education ("Iuventus Plus'' project 0478/IP3/2015/73, 2015-2016). A. V.-A. thanks Generalitat Valenciana for a PhD grant (VALi+D Program). We thank Serveis Centrals d'Instrumentacio Cientifica and the Servei d'Informatica of Universitat Jaume I for technical support and computational resources, respectively.ca_CA
dc.format.extent4 p.ca_CA
dc.language.isoengca_CA
dc.publisherRoyal Society of Chemistryca_CA
dc.relation.isPartOfChemical Communications, 2016, vol. 52, no 65ca_CA
dc.rights.urihttp://rightsstatements.org/vocab/CNE/1.0/*
dc.subjectnitroalkenesca_CA
dc.subjectepoxidationca_CA
dc.subjectnitroepoxidesca_CA
dc.titleCatalytic enantioselective epoxidation of nitroalkenesca_CA
dc.typeinfo:eu-repo/semantics/articleca_CA
dc.identifier.doihttp://dx.doi.org/10.1039/C6CC03539F
dc.rights.accessRightsinfo:eu-repo/semantics/restrictedAccessca_CA
dc.relation.publisherVersionhttp://pubs.rsc.org/-/content/articlehtml/2016/cc/c6cc03539fca_CA


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