Catalytic enantioselective epoxidation of nitroalkenes
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Scholar |
Altres documents de l'autoria: Vidal-Albalat, Andreu; Świderek, Katarzyna; Izquierdo Ferrer, Javier; Rodríguez, Santiago; Moliner, Vicent; González, Florenci
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Mostra el registre complet de l'elementcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/7053
comunitat-uji-handle3:10234/8639
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http://dx.doi.org/10.1039/C6CC03539F |
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Títol
Catalytic enantioselective epoxidation of nitroalkenesAutoria
Data de publicació
2016Editor
Royal Society of ChemistryISSN
1359-7345; 1364-548XCita bibliogràfica
VIDAL-ALBALAT, A., et al. Catalytic enantioselective epoxidation of nitroalkenes. Chemical Communications, 2016, vol. 52, no 65, p. 10060-10063.Tipus de document
info:eu-repo/semantics/articleVersió de l'editorial
http://pubs.rsc.org/-/content/articlehtml/2016/cc/c6cc03539fParaules clau / Matèries
Resum
Nitroepoxides are potentially exploitable as synthons with vicinal electrophilic centers. Nevertheless, although advances have been made in the field, enantioselective epoxidation of nitroalkenes is still a challenging ... [+]
Nitroepoxides are potentially exploitable as synthons with vicinal electrophilic centers. Nevertheless, although advances have been made in the field, enantioselective epoxidation of nitroalkenes is still a challenging process. Herein we show a convenient procedure for the preparation of optically active nitroepoxides in high enantiomeric excess and high chemical yield. The kinetic data of the best catalyst have been examined using computational methods based on DFT calculations. Interestingly, the results demonstrate that the enantioselectivity of the epoxidation of nitroalkenes by this kind of catalyst is not only kinetically but also thermodynamically controlled. [-]
Publicat a
Chemical Communications, 2016, vol. 52, no 65Drets d'accés
http://rightsstatements.org/vocab/CNE/1.0/
info:eu-repo/semantics/restrictedAccess
info:eu-repo/semantics/restrictedAccess
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