Catalytic enantioselective epoxidation of nitroalkenes
Impacto
Scholar |
Otros documentos de la autoría: Vidal-Albalat, Andreu; Świderek, Katarzyna; Izquierdo Ferrer, Javier; Rodríguez, Santiago; Moliner, Vicent; González, Florenci
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comunitat-uji-handle3:10234/8639
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http://dx.doi.org/10.1039/C6CC03539F |
Metadatos
Título
Catalytic enantioselective epoxidation of nitroalkenesAutoría
Fecha de publicación
2016Editor
Royal Society of ChemistryISSN
1359-7345; 1364-548XCita bibliográfica
VIDAL-ALBALAT, A., et al. Catalytic enantioselective epoxidation of nitroalkenes. Chemical Communications, 2016, vol. 52, no 65, p. 10060-10063.Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
http://pubs.rsc.org/-/content/articlehtml/2016/cc/c6cc03539fPalabras clave / Materias
Resumen
Nitroepoxides are potentially exploitable as synthons with vicinal electrophilic centers. Nevertheless, although advances have been made in the field, enantioselective epoxidation of nitroalkenes is still a challenging ... [+]
Nitroepoxides are potentially exploitable as synthons with vicinal electrophilic centers. Nevertheless, although advances have been made in the field, enantioselective epoxidation of nitroalkenes is still a challenging process. Herein we show a convenient procedure for the preparation of optically active nitroepoxides in high enantiomeric excess and high chemical yield. The kinetic data of the best catalyst have been examined using computational methods based on DFT calculations. Interestingly, the results demonstrate that the enantioselectivity of the epoxidation of nitroalkenes by this kind of catalyst is not only kinetically but also thermodynamically controlled. [-]
Publicado en
Chemical Communications, 2016, vol. 52, no 65Derechos de acceso
http://rightsstatements.org/vocab/CNE/1.0/
info:eu-repo/semantics/restrictedAccess
info:eu-repo/semantics/restrictedAccess
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