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A C3v-symmetrical tribenzotriquinacene-based threefold N-heterocyclic carbene. Coordination to rhodium(I) and stereoelectronic properties

dc.contributor.authorSegarra, Candela
dc.contributor.authorLinke, Jens
dc.contributor.authorMas, Elena
dc.contributor.authorKuck, Dietmar
dc.contributor.authorPeris, Eduardo
dc.date.accessioned2014-05-12T14:05:17Z
dc.date.available2014-05-12T14:05:17Z
dc.date.issued2013-09-19
dc.identifier.citationChem. Commun., 2013, 49, 10572ca_CA
dc.identifier.issn1359-7345
dc.identifier.issn1364-548X
dc.identifier.urihttp://hdl.handle.net/10234/92078
dc.description.abstractA novel tribenzotriquinacene-based tris-NHC has been obtained and coordinated to rhodium. The new ligand displays a unique rigid C3v symmetry. The electrochemical analysis of the tri-rhodium complex reveals that the three metals are essentially disconnected.ca_CA
dc.format.extent3 p.ca_CA
dc.format.mimetypeapplication/pdfca_CA
dc.language.isoengca_CA
dc.publisherRoyal Society of Chemistryca_CA
dc.relation.isPartOfChemical Communications., 2013, v.49, no. 90ca_CA
dc.rights© Royal Society of Chemistry 2014ca_CA
dc.rights.urihttp://rightsstatements.org/vocab/InC/1.0/*
dc.subjectTricarbene ligandca_CA
dc.subjectCatalytic benefitsca_CA
dc.subjectComplexesca_CA
dc.subjectIridiumca_CA
dc.subjectPalladiumca_CA
dc.titleA C3v-symmetrical tribenzotriquinacene-based threefold N-heterocyclic carbene. Coordination to rhodium(I) and stereoelectronic propertiesca_CA
dc.typeinfo:eu-repo/semantics/articleca_CA
dc.identifier.doihttp://dx.doi.org/10.1039/C3CC46155F
dc.rights.accessRightsinfo:eu-repo/semantics/restrictedAccessca_CA
dc.relation.publisherVersionhttp://pubs.rsc.org/en/content/articlelanding/2013/cc/c3cc46155f#!divAbstractca_CA
dc.type.versioninfo:eu-repo/semantics/publishedVersionca_CA


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