A C3v-symmetrical tribenzotriquinacene-based threefold N-heterocyclic carbene. Coordination to rhodium(I) and stereoelectronic properties
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Títol
A C3v-symmetrical tribenzotriquinacene-based threefold N-heterocyclic carbene. Coordination to rhodium(I) and stereoelectronic propertiesData de publicació
2013-09-19Editor
Royal Society of ChemistryISSN
1359-7345; 1364-548XCita bibliogràfica
Chem. Commun., 2013, 49, 10572Tipus de document
info:eu-repo/semantics/articleVersió de l'editorial
http://pubs.rsc.org/en/content/articlelanding/2013/cc/c3cc46155f#!divAbstractVersió
info:eu-repo/semantics/publishedVersionParaules clau / Matèries
Resum
A novel tribenzotriquinacene-based tris-NHC has been obtained and coordinated to rhodium. The new ligand displays a unique rigid C3v symmetry. The electrochemical analysis of the tri-rhodium complex reveals that the ... [+]
A novel tribenzotriquinacene-based tris-NHC has been obtained and coordinated to rhodium. The new ligand displays a unique rigid C3v symmetry. The electrochemical analysis of the tri-rhodium complex reveals that the three metals are essentially disconnected. [-]
Publicat a
Chemical Communications., 2013, v.49, no. 90Drets d'accés
© Royal Society of Chemistry 2014
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