A C3v-symmetrical tribenzotriquinacene-based threefold N-heterocyclic carbene. Coordination to rhodium(I) and stereoelectronic properties
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comunitat-uji-handle2:10234/7013
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http://dx.doi.org/10.1039/C3CC46155F |
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Title
A C3v-symmetrical tribenzotriquinacene-based threefold N-heterocyclic carbene. Coordination to rhodium(I) and stereoelectronic propertiesDate
2013-09-19Publisher
Royal Society of ChemistryISSN
1359-7345; 1364-548XBibliographic citation
Chem. Commun., 2013, 49, 10572Type
info:eu-repo/semantics/articleVersion
info:eu-repo/semantics/publishedVersionSubject
Abstract
A novel tribenzotriquinacene-based tris-NHC has been obtained and coordinated to rhodium. The new ligand displays a unique rigid C3v symmetry. The electrochemical analysis of the tri-rhodium complex reveals that the ... [+]
A novel tribenzotriquinacene-based tris-NHC has been obtained and coordinated to rhodium. The new ligand displays a unique rigid C3v symmetry. The electrochemical analysis of the tri-rhodium complex reveals that the three metals are essentially disconnected. [-]
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Chemical Communications., 2013, v.49, no. 90Rights
© Royal Society of Chemistry 2014
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- QFA_Articles [819]