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Remarkable increase in basicity associated with supramolecular gelation

dc.contributor.authorRodríguez Llansola, Francisco
dc.contributor.authorEscuder, Beatriu
dc.contributor.authorMiravet, Juan
dc.date.accessioned2011-06-03T12:07:19Z
dc.date.available2011-06-03T12:07:19Z
dc.date.issued2009
dc.identifier.citationRODRÍGUEZ-LLANSOLA, Francisco; ESCUDER, Beatriu; MIRAVET, Juan F. Remarkable increase in basicity associated with supramolecular gelation. Organic & Biomolecular Chemistry, 2009, vol. 7, no 15, p. 3091-3094.
dc.identifier.issn1477-0520
dc.identifier.urihttp://hdl.handle.net/10234/22997
dc.description.abstractL-Proline derivatives which are able to form supramolecular gels show an amazing basicity increase in the aggregated (gel) state as compared to solution. As a result they behave as enantioselective catalysts for the aldol reaction in solution but produce a base-catalyzed aldol racemisation in the gel state
dc.format.extent4. p.
dc.language.isoeng
dc.publisherRoyal Society of Chemistry
dc.rights© Royal Society of Chemistry 2009
dc.rights.urihttp://www.rsc.org/AboutUs/Copyright/index.asp
dc.source.urihttp://pubs.rsc.org/en/content/articlepdf/2009/ob/b904523f
dc.subjectBasicity
dc.subjectL-Proline derivatives
dc.subjectSupramolecular gels
dc.subjectGel
dc.subjectSolution
dc.subjectEnantioselective catalysts
dc.subject.lcshColloids--Basicity
dc.subject.lcshGelation
dc.subject.otherCol•loides--Basicitat
dc.titleRemarkable increase in basicity associated with supramolecular gelation
dc.typeinfo:eu-repo/semantics/article
dc.identifier.doihttp://dx.doi.org/10.1039/b904523f
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.relation.publisherVersionhttps://pubs.rsc.org/en/content/articlelanding/2009/ob/b904523f#!divAbstract


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