Remarkable increase in basicity associated with supramolecular gelation
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Título
Remarkable increase in basicity associated with supramolecular gelationFecha de publicación
2009Editor
Royal Society of ChemistryISSN
1477-0520Cita bibliográfica
RODRÍGUEZ-LLANSOLA, Francisco; ESCUDER, Beatriu; MIRAVET, Juan F. Remarkable increase in basicity associated with supramolecular gelation. Organic & Biomolecular Chemistry, 2009, vol. 7, no 15, p. 3091-3094.Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
https://pubs.rsc.org/en/content/articlelanding/2009/ob/b904523f#!divAbstractPalabras clave / Materias
Resumen
L-Proline derivatives which are able to form supramolecular gels show an amazing basicity increase in
the aggregated (gel) state as compared to solution. As a result they behave as enantioselective catalysts
for the ... [+]
L-Proline derivatives which are able to form supramolecular gels show an amazing basicity increase in
the aggregated (gel) state as compared to solution. As a result they behave as enantioselective catalysts
for the aldol reaction in solution but produce a base-catalyzed aldol racemisation in the gel state [-]
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© Royal Society of Chemistry 2009
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