Remarkable increase in basicity associated with supramolecular gelation
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comunitat-uji-handle2:10234/7053
comunitat-uji-handle3:10234/8639
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Title
Remarkable increase in basicity associated with supramolecular gelationDate
2009Publisher
Royal Society of ChemistryISSN
1477-0520Bibliographic citation
RODRÍGUEZ-LLANSOLA, Francisco; ESCUDER, Beatriu; MIRAVET, Juan F. Remarkable increase in basicity associated with supramolecular gelation. Organic & Biomolecular Chemistry, 2009, vol. 7, no 15, p. 3091-3094.Type
info:eu-repo/semantics/articleSubject
Abstract
L-Proline derivatives which are able to form supramolecular gels show an amazing basicity increase in
the aggregated (gel) state as compared to solution. As a result they behave as enantioselective catalysts
for the ... [+]
L-Proline derivatives which are able to form supramolecular gels show an amazing basicity increase in
the aggregated (gel) state as compared to solution. As a result they behave as enantioselective catalysts
for the aldol reaction in solution but produce a base-catalyzed aldol racemisation in the gel state [-]
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