Ruthenium(II) pincer complexes featuring an anionicCNC bis(1,2,3-triazol-5-ylidene)carbazolide ligand coordinatedin a meridional fashion
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comunitat-uji-handle2:10234/160292
comunitat-uji-handle3:10234/160293
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INVESTIGACIONMetadata
Title
Ruthenium(II) pincer complexes featuring an anionicCNC bis(1,2,3-triazol-5-ylidene)carbazolide ligand coordinatedin a meridional fashionDate
2018Publisher
ElsevierISSN
0277-5387; 1873-3719Type
info:eu-repo/semantics/articlePublisher version
https://www.sciencedirect.com/science/article/pii/S027753871730493XVersion
info:eu-repo/semantics/acceptedVersionSubject
Abstract
The preparation of a new neutral ruthenium(II) pincer complexes with formula [RuCl(CO)2(CTRZNCTRZ)]
(CNC = bis(1,2,3-triazol-5-ylidene)carbazolide) is described. Access to the hydrido complex [RuH
(CO)2(CTRZNCTRZ)] ... [+]
The preparation of a new neutral ruthenium(II) pincer complexes with formula [RuCl(CO)2(CTRZNCTRZ)]
(CNC = bis(1,2,3-triazol-5-ylidene)carbazolide) is described. Access to the hydrido complex [RuH
(CO)2(CTRZNCTRZ)] was attained by reaction of the pincer ligand precursor with base and with [RuCl(H)
(AsPh3)3(CO)] in the presence of CO atmosphere. The meridional geometry pincer ligand in the complexes
is confirmed by a single crystal X-ray diffraction study of [RuCl(CO)2(CTRZNCTRZ)]. Preliminary results of
the use of [RuCl(CO)2(CTRZNCTRZ)] as catalyst in the transfer hydrogenation reaction of ketones, are
reported. [-]
Is part of
Polyhedron 143 (2018)Investigation project
IJCI-2015- 23407 ; CTQ2014-51999-P ; P11B2014-02 ;Rights
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