Ruthenium(II) pincer complexes featuring an anionicCNC bis(1,2,3-triazol-5-ylidene)carbazolide ligand coordinatedin a meridional fashion
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Altres documents de l'autoria: Kleinhans, George; Guisado-Barrios, Gregorio; Peris, Eduardo; Bezuidenhout, Daniela
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Mostra el registre complet de l'elementcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/160292
comunitat-uji-handle3:10234/160293
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Títol
Ruthenium(II) pincer complexes featuring an anionicCNC bis(1,2,3-triazol-5-ylidene)carbazolide ligand coordinatedin a meridional fashionData de publicació
2018Editor
ElsevierISSN
0277-5387; 1873-3719Tipus de document
info:eu-repo/semantics/articleVersió de l'editorial
https://www.sciencedirect.com/science/article/pii/S027753871730493XVersió
info:eu-repo/semantics/acceptedVersionParaules clau / Matèries
Resum
The preparation of a new neutral ruthenium(II) pincer complexes with formula [RuCl(CO)2(CTRZNCTRZ)]
(CNC = bis(1,2,3-triazol-5-ylidene)carbazolide) is described. Access to the hydrido complex [RuH
(CO)2(CTRZNCTRZ)] ... [+]
The preparation of a new neutral ruthenium(II) pincer complexes with formula [RuCl(CO)2(CTRZNCTRZ)]
(CNC = bis(1,2,3-triazol-5-ylidene)carbazolide) is described. Access to the hydrido complex [RuH
(CO)2(CTRZNCTRZ)] was attained by reaction of the pincer ligand precursor with base and with [RuCl(H)
(AsPh3)3(CO)] in the presence of CO atmosphere. The meridional geometry pincer ligand in the complexes
is confirmed by a single crystal X-ray diffraction study of [RuCl(CO)2(CTRZNCTRZ)]. Preliminary results of
the use of [RuCl(CO)2(CTRZNCTRZ)] as catalyst in the transfer hydrogenation reaction of ketones, are
reported. [-]
Publicat a
Polyhedron 143 (2018)Proyecto de investigación
IJCI-2015- 23407 ; CTQ2014-51999-P ; P11B2014-02 ;Drets d'accés
0277-5387/ © 2017 Elsevier Ltd. All rights reserved.
http://rightsstatements.org/vocab/InC/1.0/
info:eu-repo/semantics/openAccess
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info:eu-repo/semantics/openAccess
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