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Ruthenium(II) pincer complexes featuring an anionicCNC bis(1,2,3-triazol-5-ylidene)carbazolide ligand coordinatedin a meridional fashion
dc.contributor.author | Kleinhans, George | |
dc.contributor.author | Guisado-Barrios, Gregorio | |
dc.contributor.author | Peris, Eduardo | |
dc.contributor.author | Bezuidenhout, Daniela | |
dc.date.accessioned | 2018-06-25T10:07:15Z | |
dc.date.available | 2018-06-25T10:07:15Z | |
dc.date.issued | 2018 | |
dc.identifier.issn | 0277-5387 | |
dc.identifier.issn | 1873-3719 | |
dc.identifier.uri | http://hdl.handle.net/10234/175324 | |
dc.description.abstract | The preparation of a new neutral ruthenium(II) pincer complexes with formula [RuCl(CO)2(CTRZNCTRZ)] (CNC = bis(1,2,3-triazol-5-ylidene)carbazolide) is described. Access to the hydrido complex [RuH (CO)2(CTRZNCTRZ)] was attained by reaction of the pincer ligand precursor with base and with [RuCl(H) (AsPh3)3(CO)] in the presence of CO atmosphere. The meridional geometry pincer ligand in the complexes is confirmed by a single crystal X-ray diffraction study of [RuCl(CO)2(CTRZNCTRZ)]. Preliminary results of the use of [RuCl(CO)2(CTRZNCTRZ)] as catalyst in the transfer hydrogenation reaction of ketones, are reported. | ca_CA |
dc.format.extent | 6 p. | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | Elsevier | ca_CA |
dc.relation.isPartOf | Polyhedron 143 (2018) | ca_CA |
dc.rights | 0277-5387/ © 2017 Elsevier Ltd. All rights reserved. | ca_CA |
dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | * |
dc.subject | Ruthenium(II) | ca_CA |
dc.subject | Mesoionic carbene (MIC) | ca_CA |
dc.subject | Pincer ligands | ca_CA |
dc.subject | 1,2,3-Triazol-5-ylidene (TRZ) | ca_CA |
dc.subject | Meridional coordination | ca_CA |
dc.title | Ruthenium(II) pincer complexes featuring an anionicCNC bis(1,2,3-triazol-5-ylidene)carbazolide ligand coordinatedin a meridional fashion | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | https://doi.org/10.1016/j.poly.2017.07.010 | |
dc.relation.projectID | IJCI-2015- 23407 ; CTQ2014-51999-P ; P11B2014-02 ; | ca_CA |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | ca_CA |
dc.relation.publisherVersion | https://www.sciencedirect.com/science/article/pii/S027753871730493X | ca_CA |
dc.date.embargoEndDate | 2019-07-15 | |
dc.type.version | info:eu-repo/semantics/acceptedVersion | ca_CA |
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