Catalytic enantioselective epoxidation of nitroalkenes
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comunitat-uji-handle2:10234/7053
comunitat-uji-handle3:10234/8639
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http://dx.doi.org/10.1039/C6CC03539F |
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Title
Catalytic enantioselective epoxidation of nitroalkenesAuthor (s)
Date
2016Publisher
Royal Society of ChemistryISSN
1359-7345; 1364-548XBibliographic citation
VIDAL-ALBALAT, A., et al. Catalytic enantioselective epoxidation of nitroalkenes. Chemical Communications, 2016, vol. 52, no 65, p. 10060-10063.Type
info:eu-repo/semantics/articlePublisher version
http://pubs.rsc.org/-/content/articlehtml/2016/cc/c6cc03539fSubject
Abstract
Nitroepoxides are potentially exploitable as synthons with vicinal electrophilic centers. Nevertheless, although advances have been made in the field, enantioselective epoxidation of nitroalkenes is still a challenging ... [+]
Nitroepoxides are potentially exploitable as synthons with vicinal electrophilic centers. Nevertheless, although advances have been made in the field, enantioselective epoxidation of nitroalkenes is still a challenging process. Herein we show a convenient procedure for the preparation of optically active nitroepoxides in high enantiomeric excess and high chemical yield. The kinetic data of the best catalyst have been examined using computational methods based on DFT calculations. Interestingly, the results demonstrate that the enantioselectivity of the epoxidation of nitroalkenes by this kind of catalyst is not only kinetically but also thermodynamically controlled. [-]
Is part of
Chemical Communications, 2016, vol. 52, no 65Rights
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info:eu-repo/semantics/restrictedAccess
info:eu-repo/semantics/restrictedAccess
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