First homoleptic MIC and heteroleptic NHC-MIC coordination cages from 1,3,5-triphenylbenzene-bridged tris-MIC and tris-NHC ligands
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Otros documentos de la autoría: Mejuto, Carmen; Guisado-Barrios, Gregorio; Gusev, Dmitry; Peris, Eduardo
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Mostrar el registro completo del ítemcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/7053
comunitat-uji-handle3:10234/141972
comunitat-uji-handle4:10234/141976
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Título
First homoleptic MIC and heteroleptic NHC-MIC coordination cages from 1,3,5-triphenylbenzene-bridged tris-MIC and tris-NHC ligandsFecha de publicación
2015-07-24Editor
Royal Society of ChemistryCita bibliográfica
Chem. Commun., 2015, 51, 13914Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
http://pubs.rsc.org/en/content/articlepdf/2015/cc/c5cc05114bPalabras clave / Materias
Resumen
The preparation of a triphenylbenzene-bridged tris-(1,2,3-triazolium)
salt allowed us to obtain the first homoleptic tris-MIC cylinder-like
cages of Ag and Au. The silver MIC-based cage reacts with the trisNHC-Ag
... [+]
The preparation of a triphenylbenzene-bridged tris-(1,2,3-triazolium)
salt allowed us to obtain the first homoleptic tris-MIC cylinder-like
cages of Ag and Au. The silver MIC-based cage reacts with the trisNHC-Ag
analogue to form the corresponding heteroleptic NHC–MIC
silver cage in an unusual reaction involving the simultaneous
exchange of the tris-NHC and tris-MIC ligands. [-]
Publicado en
Chemical Communication, 2015, 51Derechos de acceso
info:eu-repo/semantics/openAccess
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