First homoleptic MIC and heteroleptic NHC-MIC coordination cages from 1,3,5-triphenylbenzene-bridged tris-MIC and tris-NHC ligands
![Thumbnail](/xmlui/bitstream/handle/10234/142045/10.1039%3ac5cc05114b.pdf.jpg?sequence=4&isAllowed=y)
View/ Open
Impact
![Google Scholar](/xmlui/themes/Mirage2/images/uji/logo_google.png)
![Microsoft Academico](/xmlui/themes/Mirage2/images/uji/logo_microsoft.png)
Metadata
Show full item recordcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/7053
comunitat-uji-handle3:10234/141972
comunitat-uji-handle4:10234/141976
INVESTIGACIONMetadata
Title
First homoleptic MIC and heteroleptic NHC-MIC coordination cages from 1,3,5-triphenylbenzene-bridged tris-MIC and tris-NHC ligandsDate
2015-07-24Publisher
Royal Society of ChemistryBibliographic citation
Chem. Commun., 2015, 51, 13914Type
info:eu-repo/semantics/articlePublisher version
http://pubs.rsc.org/en/content/articlepdf/2015/cc/c5cc05114bSubject
Abstract
The preparation of a triphenylbenzene-bridged tris-(1,2,3-triazolium)
salt allowed us to obtain the first homoleptic tris-MIC cylinder-like
cages of Ag and Au. The silver MIC-based cage reacts with the trisNHC-Ag
... [+]
The preparation of a triphenylbenzene-bridged tris-(1,2,3-triazolium)
salt allowed us to obtain the first homoleptic tris-MIC cylinder-like
cages of Ag and Au. The silver MIC-based cage reacts with the trisNHC-Ag
analogue to form the corresponding heteroleptic NHC–MIC
silver cage in an unusual reaction involving the simultaneous
exchange of the tris-NHC and tris-MIC ligands. [-]
Is part of
Chemical Communication, 2015, 51Rights
info:eu-repo/semantics/openAccess
This item appears in the folowing collection(s)
- QOMCAT_ Articles [9]