First homoleptic MIC and heteroleptic NHC-MIC coordination cages from 1,3,5-triphenylbenzene-bridged tris-MIC and tris-NHC ligands
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Mostra el registre complet de l'elementcomunitat-uji-handle:10234/9
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Títol
First homoleptic MIC and heteroleptic NHC-MIC coordination cages from 1,3,5-triphenylbenzene-bridged tris-MIC and tris-NHC ligandsData de publicació
2015-07-24Editor
Royal Society of ChemistryCita bibliogràfica
Chem. Commun., 2015, 51, 13914Tipus de document
info:eu-repo/semantics/articleVersió de l'editorial
http://pubs.rsc.org/en/content/articlepdf/2015/cc/c5cc05114bParaules clau / Matèries
Resum
The preparation of a triphenylbenzene-bridged tris-(1,2,3-triazolium)
salt allowed us to obtain the first homoleptic tris-MIC cylinder-like
cages of Ag and Au. The silver MIC-based cage reacts with the trisNHC-Ag
... [+]
The preparation of a triphenylbenzene-bridged tris-(1,2,3-triazolium)
salt allowed us to obtain the first homoleptic tris-MIC cylinder-like
cages of Ag and Au. The silver MIC-based cage reacts with the trisNHC-Ag
analogue to form the corresponding heteroleptic NHC–MIC
silver cage in an unusual reaction involving the simultaneous
exchange of the tris-NHC and tris-MIC ligands. [-]
Publicat a
Chemical Communication, 2015, 51Drets d'accés
info:eu-repo/semantics/openAccess
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