First homoleptic MIC and heteroleptic NHC-MIC coordination cages from 1,3,5-triphenylbenzene-bridged tris-MIC and tris-NHC ligands
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Other documents of the author: Mejuto, Carmen; Guisado-Barrios, Gregorio; Gusev, Dmitry; Peris, Eduardo
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Show full item recordcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/7053
comunitat-uji-handle3:10234/141972
comunitat-uji-handle4:10234/141976
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Title
First homoleptic MIC and heteroleptic NHC-MIC coordination cages from 1,3,5-triphenylbenzene-bridged tris-MIC and tris-NHC ligandsDate
2015-07-24Publisher
Royal Society of ChemistryBibliographic citation
Chem. Commun., 2015, 51, 13914Type
info:eu-repo/semantics/articlePublisher version
http://pubs.rsc.org/en/content/articlepdf/2015/cc/c5cc05114bSubject
Abstract
The preparation of a triphenylbenzene-bridged tris-(1,2,3-triazolium)
salt allowed us to obtain the first homoleptic tris-MIC cylinder-like
cages of Ag and Au. The silver MIC-based cage reacts with the trisNHC-Ag
... [+]
The preparation of a triphenylbenzene-bridged tris-(1,2,3-triazolium)
salt allowed us to obtain the first homoleptic tris-MIC cylinder-like
cages of Ag and Au. The silver MIC-based cage reacts with the trisNHC-Ag
analogue to form the corresponding heteroleptic NHC–MIC
silver cage in an unusual reaction involving the simultaneous
exchange of the tris-NHC and tris-MIC ligands. [-]
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Chemical Communication, 2015, 51Rights
info:eu-repo/semantics/openAccess
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- QOMCAT_ Articles [9]