Isolation of a potassium bis(1,2,3-triazol-5-ylidene) carbazolide: a stabilizing pincer ligand for reactive late transition metal complexes
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Otros documentos de la autoría: Bezuidenhout, Daniela; Kleinhans, George; Guisado-Barrios, Gregorio; Liles, David C.; Üng, Gaël; Bertrand, Guy
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Mostrar el registro completo del ítemcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/7053
comunitat-uji-handle3:10234/8639
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INVESTIGACIONMetadatos
Título
Isolation of a potassium bis(1,2,3-triazol-5-ylidene) carbazolide: a stabilizing pincer ligand for reactive late transition metal complexesAutoría
Fecha de publicación
2014Editor
Royal Society of ChemistryISSN
1359-7345; 1364-548XTipo de documento
info:eu-repo/semantics/articleVersión de la editorial
http://pubs.rsc.org/en/content/articlelanding/2014/cc/c3cc49385g#!divAbstractPalabras clave / Materias
Resumen
The synthesis and X-ray crystal structure of a potassium adduct of a monoanionic CNC-pincer ligand featuring two mesoionic carbenes is reported. Owing to the peculiar electronic and steric properties of this ligand, ... [+]
The synthesis and X-ray crystal structure of a potassium adduct of a monoanionic CNC-pincer ligand featuring two mesoionic carbenes is reported. Owing to the peculiar electronic and steric properties of this ligand, the first neutral stable Ni(II)-hydride, and an unusual Cu(II) complex displaying a seesaw geometry, have been isolated. [-]
Publicado en
Chemical Communications, 2014, 50Derechos de acceso
© Royal Society of Chemistry 2015
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info:eu-repo/semantics/openAccess
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info:eu-repo/semantics/openAccess
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