Isolation of a potassium bis(1,2,3-triazol-5-ylidene) carbazolide: a stabilizing pincer ligand for reactive late transition metal complexes
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Títol
Isolation of a potassium bis(1,2,3-triazol-5-ylidene) carbazolide: a stabilizing pincer ligand for reactive late transition metal complexesAutoria
Data de publicació
2014Editor
Royal Society of ChemistryISSN
1359-7345; 1364-548XTipus de document
info:eu-repo/semantics/articleVersió de l'editorial
http://pubs.rsc.org/en/content/articlelanding/2014/cc/c3cc49385g#!divAbstractParaules clau / Matèries
Resum
The synthesis and X-ray crystal structure of a potassium adduct of a monoanionic CNC-pincer ligand featuring two mesoionic carbenes is reported. Owing to the peculiar electronic and steric properties of this ligand, ... [+]
The synthesis and X-ray crystal structure of a potassium adduct of a monoanionic CNC-pincer ligand featuring two mesoionic carbenes is reported. Owing to the peculiar electronic and steric properties of this ligand, the first neutral stable Ni(II)-hydride, and an unusual Cu(II) complex displaying a seesaw geometry, have been isolated. [-]
Publicat a
Chemical Communications, 2014, 50Drets d'accés
© Royal Society of Chemistry 2015
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info:eu-repo/semantics/openAccess
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