Isolation of a potassium bis(1,2,3-triazol-5-ylidene) carbazolide: a stabilizing pincer ligand for reactive late transition metal complexes
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Show full item recordcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/7053
comunitat-uji-handle3:10234/8639
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Title
Isolation of a potassium bis(1,2,3-triazol-5-ylidene) carbazolide: a stabilizing pincer ligand for reactive late transition metal complexesAuthor (s)
Date
2014Publisher
Royal Society of ChemistryISSN
1359-7345; 1364-548XType
info:eu-repo/semantics/articleSubject
Abstract
The synthesis and X-ray crystal structure of a potassium adduct of a monoanionic CNC-pincer ligand featuring two mesoionic carbenes is reported. Owing to the peculiar electronic and steric properties of this ligand, ... [+]
The synthesis and X-ray crystal structure of a potassium adduct of a monoanionic CNC-pincer ligand featuring two mesoionic carbenes is reported. Owing to the peculiar electronic and steric properties of this ligand, the first neutral stable Ni(II)-hydride, and an unusual Cu(II) complex displaying a seesaw geometry, have been isolated. [-]
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Chemical Communications, 2014, 50Rights
© Royal Society of Chemistry 2015
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