Synthesis and structure of a paramagnetic Mo3S4 incomplete cuboidal cluster with seven cluster skeletal electrons
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Otros documentos de la autoría: Petrov, Pavel A.; Naumov, Dmitry Yu; Llusar, Rosa; Gómez García, Carlos J.; Polo Ortiz, Victoriano; Konchenko, Sergey N.
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Título
Synthesis and structure of a paramagnetic Mo3S4 incomplete cuboidal cluster with seven cluster skeletal electronsAutoría
Fecha de publicación
2012-08Editor
Royal Society of ChemistryTipo de documento
info:eu-repo/semantics/articleVersión de la editorial
http://pubs.rsc.org/en/content/articlelanding/2012/dt/c2dt31577gVersión
info:eu-repo/semantics/publishedVersionResumen
The electron precise incomplete cuboidal complex [Mo3S4(dppe)3Br3]Br (1a) with 6 cluster skeletal electrons (CSE) and its halogen-mixed analogue [Mo3S4(dppe)3(Br,Cl)3](Br,Cl) (1b) can be smoothly reduced to the ... [+]
The electron precise incomplete cuboidal complex [Mo3S4(dppe)3Br3]Br (1a) with 6 cluster skeletal electrons (CSE) and its halogen-mixed analogue [Mo3S4(dppe)3(Br,Cl)3](Br,Cl) (1b) can be smoothly reduced to the paramagnetic [Mo3S4(dppe)3X3] clusters (2a, X = Br; 2b, X = Cl/Br) with 7 CSE by treatment with liquid Ga. [-]
Publicado en
Dalton Transactions. 2012, 41Derechos de acceso
© The Royal Society of Chemistry 2012
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