Listar por autoría "b0b7eaa1-bc61-4a2f-9f1b-1315e59982d9"
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Selective synthesis of triangular cluster oxido-sulfidocomplexes of Mo and W: High yield preparations of [Mo3O2S2(H2O)9]4+, [W3O2S2(H2O)9]4+, [W2MoO2S2(H2O)9]4+ and their derivatization
Abramov, Pavel A.; Sokolov, Maxim; Hernández Molina, Rita; Vicent Barrera, Cristian; Virovets, Alexander V.; Naumov, Dmitry Yu; Gili, Pedro; González Platas, Javier; Fedin, Vladimir P. Elsevier (2010)Reaction of [Mo2O2(μ-S)2(H2O)6]2+ with Mo(CO)6 or metallic Mo under hydrothermal conditions (140 °C, 4 M HCl) gives oxido-sulfido cluster aqua complex [Mo3(μ3-S)(μ-O)2(μ-S)(H2O)9]4+ (1). Similarly, [W3(μ3-S)(μ-O)2(μ-S)(H2O)9]4+ ... -
Synthesis and structure of a paramagnetic Mo3S4 incomplete cuboidal cluster with seven cluster skeletal electrons
Petrov, Pavel A.; Naumov, Dmitry Yu; Llusar, Rosa; Gómez García, Carlos J.; Polo Ortiz, Victoriano; Konchenko, Sergey N. Royal Society of Chemistry (2012-08)The electron precise incomplete cuboidal complex [Mo3S4(dppe)3Br3]Br (1a) with 6 cluster skeletal electrons (CSE) and its halogen-mixed analogue [Mo3S4(dppe)3(Br,Cl)3](Br,Cl) (1b) can be smoothly reduced to the paramagnetic ... -
Synthesis, molecular structures and EPR spectra of the paramagnetic cuboidal clusters with Mo3S4Ga cores
Petrov, Pavel A.; Naumov, Dmitry Yu.; Sukhikh, Taisiya S.; Konchenko, Sergey N.; Gómez García, Carlos J.; Llusar, Rosa Royal Society of Chemistry (2017)Electron precise [Mo3(l3-S)(l-S)3(diphos)3Br3]Br (diphos = dppe, dmpe) incomplete cuboidal clusters with six cluster skeletal electrons (CSE) were converted into paramagnetic cuboidal [Mo3(GaBr)(l3-S)4- (diphos)3Br3] ...