Effect of nanostructured electrode architecture and semiconductor deposition strategy on the photovoltaic performance of quantum dot sensitized solar cells
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Otros documentos de la autoría: Samadpour, Mahmoud; Gimenez, Sixto; Pérez Boix, Pablo; Shen, Qing; Calvo, Mauricio E.; Taghavinia, Nima; Iraji Zad, Azam; toyoda, taro; Míguez, Hernán; Mora-Sero, Ivan
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Mostrar el registro completo del ítemcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/2507
comunitat-uji-handle3:10234/6973
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INVESTIGACIONMetadatos
Título
Effect of nanostructured electrode architecture and semiconductor deposition strategy on the photovoltaic performance of quantum dot sensitized solar cellsAutoría
Fecha de publicación
2012Editor
ElsevierISSN
0013-4686Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
http://www.sciencedirect.com/science/article/pii/S0013468612006573Versión
info:eu-repo/semantics/submittedVersionPalabras clave / Materias
Resumen
Here we analyze the effect of two relevant aspects related to cell preparation on quantum dot sensitized solar cells (QDSCs) performance: the architecture of the TiO2 nanostructured electrode and the growth method of ... [+]
Here we analyze the effect of two relevant aspects related to cell preparation on quantum dot sensitized solar cells (QDSCs) performance: the architecture of the TiO2 nanostructured electrode and the growth method of quantum dots (QD). Particular attention is given to the effect on the photovoltage, Voc, since this parameter conveys the main current limitation of QDSCs. We have analyzed electrodes directly sensitized with CdSe QDs grown by chemical bath deposition (CBD) and successive ionic layer adsorption and reaction (SILAR). We have carried out a systematic study comprising structural, optical, photophysical and photoelectrochemical characterization in order to correlate the material properties of the photoanodes with the functional performance of the manufactured QDSCs. The results show that the correspondence between photovoltaic conversion efficiency and the surface area of TiO2 depends on the QDs deposition method. Higher Voc values are systematically obtained for TiO2 morphologies with decreasing surface area and for cells using CBD growth method. This is systematically correlated to a higher recombination resistance of CBD sensitized electrodes. Electron injection kinetics from QDs into TiO2 also depends on both the TiO2 structure and the QDs deposition method, being systematically faster for CBD. Only for electrodes prepared with small TiO2 nanoparticles SILAR method presents better performance than CBD, indicating that the small pore size disturb the CBD growth method. These results have important implications for the optimization of QDSCs. [-]
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Electrochimica Acta. July 2012, Volume 75, 30Derechos de acceso
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