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dc.contributor.authorSabater Serra, Roser
dc.contributor.authorGómez Tejedor, J. A.
dc.contributor.authorCorreia, D. M.
dc.contributor.authorDe Zea Bermúdez, Verónica
dc.contributor.authorAndrio, Andreu
dc.contributor.authorMeseguer Dueñas, José María
dc.contributor.authorGómez Ribelles, José Luis
dc.contributor.authorLanceros Méndez, S.
dc.contributor.authorCosta, C. M.
dc.date.accessioned2019-02-19T10:16:01Z
dc.date.available2019-02-19T10:16:01Z
dc.date.issued2018
dc.identifier.citationCORREIA, D. M., et al. Ionic and conformational mobility in poly (vinylidene fluoride)/ionic liquid blends: Dielectric and electrical conductivity behavior. Polymer, 2018, vol. 143, p. 164-172.ca_CA
dc.identifier.issn0032-3861
dc.identifier.urihttp://hdl.handle.net/10234/181258
dc.description.abstractThe glass transition dynamics and the charge transport for blends composed of poly(vinylidenefluoride)(PVDF) and the ionic liquid (IL) 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl) imide, [Emim][TFSI] have been investigated as a function of different IL content (0, 10, 25 and 40 % wt) by differentialscanning calorimetry (DSC), dynamic-mechanical analysis (DMA) and broadband dielectric relaxationspectroscopy (BDS) in wide frequency and temperature ranges (0.1 Hze1 MHz and 120 to 150 C,respectively). The inclusion of the IL in the polymer matrix affected the main relaxation process (b-relaxation) of the amorphous phase of the polymer matrix detected with all the techniques employed. Itis demonstrated, that the chain segments of PVDF and the IL are mixed at the nanometer range. Theblends were homogeneous regardless of the amount of IL and the glass transition temperature (Tg)shifted to lower temperatures as the IL content was increased. A good agreement between the Tgmeasured by BDS and DSC was observed for all PVDF/IL samples. The conductivity formalism revealedsignificant contributions of the IL concentration to the conductivity behavior of the blends in that isdescribed by charge motion and electrode polarization effects. The activation energy of all the PVDF/ILsamples, calculated by Dyre model, decreased with IL addition with respect to that of neat PVDF.ca_CA
dc.format.extent9 p.ca_CA
dc.language.isoengca_CA
dc.publisherElsevierca_CA
dc.relation.isPartOfPolymer 143 (2018)ca_CA
dc.rights0032-3861/©2018 Elsevier Ltd. All rights reservedca_CA
dc.subjectPVDFca_CA
dc.subjectIonic liquidca_CA
dc.subjectDielectric responseca_CA
dc.subjectConductivityca_CA
dc.subjectElectric modulusca_CA
dc.titleIonic and conformational mobility in poly(vinylidene fluoride)/ionic liquid blends: Dielectric and electrical conductivity behaviorca_CA
dc.typeinfo:eu-repo/semantics/articleca_CA
dc.identifier.doihttps://doi.org/10.1016/j.polymer.2018.04.019
dc.relation.projectIDUID/FIS/04650/201 ; DC/CTM-ENE/5387/2014, PTDC/EEI-SII/5582/2014 and UID/CTM/50025/2013 and Grants SFRH/BPD/121526/2016 (D.M.C.), SFRH/BPD/112547/2015 (C.M.C.). ; MAT2016-76039-C4-3-R (AEI/FEDER, UEca_CA
dc.rights.accessRightsinfo:eu-repo/semantics/restrictedAccessca_CA
dc.relation.publisherVersionhttps://www.sciencedirect.com/science/article/pii/S0032386118303069ca_CA
dc.type.versioninfo:eu-repo/semantics/publishedVersionca_CA


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