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Regioselective Opening of Nitroepoxides with Unsymmetrical Diamines
dc.contributor.author | Nosood, Yazdanbakhsh L. | |
dc.contributor.author | Halimehjani, Azim Ziyaei | |
dc.contributor.author | González, Florenci | |
dc.date.accessioned | 2018-06-13T10:29:46Z | |
dc.date.available | 2018-06-13T10:29:46Z | |
dc.date.issued | 2018-01 | |
dc.identifier.citation | NOSOOD, Yazdanbakhsh Lotfi; ZIYAEI HALIMEHJANI, Azim; GONZÁLEZ, Florenci V. Regioselective Opening of Nitroepoxides with Unsymmetrical Diamines. The Journal of organic chemistry, 2018. | ca_CA |
dc.identifier.uri | http://hdl.handle.net/10234/175134 | |
dc.description.abstract | Nitroepoxides are easily transformed into benzodiazepines, tetrahydrobenzodiazepines, imidazopyridines, and N-alkyl tetrahydroquinoxalines by treatment with 2-aminobenzylamines, 2-aminopyridines, and N-alkyl 1,2-diaminobenzenes, respectively. Regioselectivity is controlled through attack of the most nucleophilic nitrogen of the unsymmetrical diamine to the β position of the epoxide. These reactions represent an efficient way to prepare privileged bioactive structures. | ca_CA |
dc.format.extent | 6 p. | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | American Chemical Society | ca_CA |
dc.rights | Copyright © 2018 American Chemical Society | ca_CA |
dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | * |
dc.subject | steel beams and girders | ca_CA |
dc.subject | benzodiazepines | ca_CA |
dc.subject | beta position | ca_CA |
dc.subject | imidazopyridines | ca_CA |
dc.subject | regio-selective | ca_CA |
dc.title | Regioselective Opening of Nitroepoxides with Unsymmetrical Diamines | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | https://doi.org/10.1021/acs.joc.7b02795 | |
dc.relation.projectID | Generalitat Valenciana (AICO/ 2016/32) | ca_CA |
dc.rights.accessRights | info:eu-repo/semantics/restrictedAccess | ca_CA |
dc.relation.publisherVersion | https://pubs.acs.org/doi/abs/10.1021/acs.joc.7b02795 | ca_CA |
dc.type.version | info:eu-repo/semantics/publishedVersion | ca_CA |
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