Regioselective Opening of Nitroepoxides with Unsymmetrical Diamines
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Otros documentos de la autoría: Nosood, Yazdanbakhsh L.; Halimehjani, Azim Ziyaei; González, Florenci
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https://doi.org/10.1021/acs.joc.7b02795 |
Metadatos
Título
Regioselective Opening of Nitroepoxides with Unsymmetrical DiaminesFecha de publicación
2018-01Editor
American Chemical SocietyCita bibliográfica
NOSOOD, Yazdanbakhsh Lotfi; ZIYAEI HALIMEHJANI, Azim; GONZÁLEZ, Florenci V. Regioselective Opening of Nitroepoxides with Unsymmetrical Diamines. The Journal of organic chemistry, 2018.Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
https://pubs.acs.org/doi/abs/10.1021/acs.joc.7b02795Versión
info:eu-repo/semantics/publishedVersionPalabras clave / Materias
Resumen
Nitroepoxides are easily transformed into benzodiazepines, tetrahydrobenzodiazepines, imidazopyridines, and N-alkyl tetrahydroquinoxalines by treatment with 2-aminobenzylamines, 2-aminopyridines, and N-alkyl 1,2-dia ... [+]
Nitroepoxides are easily transformed into benzodiazepines, tetrahydrobenzodiazepines, imidazopyridines, and N-alkyl tetrahydroquinoxalines by treatment with 2-aminobenzylamines, 2-aminopyridines, and N-alkyl 1,2-diaminobenzenes, respectively. Regioselectivity is controlled through attack of the most nucleophilic nitrogen of the unsymmetrical diamine to the β position of the epoxide. These reactions represent an efficient way to prepare privileged bioactive structures. [-]
Proyecto de investigación
Generalitat Valenciana (AICO/ 2016/32)Derechos de acceso
Copyright © 2018
American Chemical Society
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