Listar Institute of Advanced Materials (INAM) por título
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Catalyst design for highly efficient carbon dioxide hydrogenation to formic acid under buffering conditions
Elsevier (2020-03-19)We report on new ruthenium complexes as catalysts for the efficient transformation of CO2 into formic acid employing basic ionic liquids as buffering media. Remarkably, these complexes catalyze the hydrogenation of CO2 ... -
Catalytic conversion of alkynes to α-vinyl sulfides mediated by carbene-linker-carbene (CXC) rhodium and iridium complexes
The Royal Society of Chemistry (2021-01-21)The catalytic activity of a set of mono- and bimetallic Rh(I) and Ir(I) complexes bearing carbene-linker-carbene (CXC) bis-triazolylidene ligands (with X = O, N) coordinated in a bridging or chelating fashion was evaluated ... -
Categorical Variable Mapping Considerations in Classification Problems: Protein Application
MDPI (2023)The mapping of categorical variables into numerical values is common in machine learning classification problems. This type of mapping is frequently performed in a relatively arbitrary manner. We present a series of four ... -
Cation-Driven Self-Assembly of a Gold(I)-Based Metallo-Tweezer
Wiley (2017-08-07)A combination of self-complementary pi-pi-stacking interactions and metallophilic interactions triggered the self-assembly of a new digold(I) metallo-tweezer in the presence of several types of M+ ions. Titrations by ... -
Caught in Action: X-ray Structure of Thymidylate Synthase with Noncovalent Intermediate Analog
American Chemical Society (2021-04-08)Methylation of 2-deoxyuridine-5′-monophosphate (dUMP) at the C5 position by the obligate dimeric thymidylate synthase (TSase) in the sole de novo biosynthetic pathway to thymidine 5′-monophosphate (dTMP) proceeds by forming ... -
Changes from Bulk to Surface Recombination Mechanisms between Pristine and Cycled Perovskite Solar Cells
American Chemical Society (2017)Several aspects on the photophysical characterization of lead halide hybrid organic–inorganic perovskite solar cells remain unsolved. It has been observed that ionic transport and polarization of the interfaces cause very ... -
Characterization of Aerosol Deposited Cesium Lead Tribromide Perovskite Films on Interdigited ITO Electrodes
John Wiley & Sons (2021-01-15)Aerosol deposition (AD) is a promising additive manufacturing method to fabricate low-cost, scalable films at room temperature, but has not been considered for semiconductor processing, so far. The successful preparation ... -
Chemi-Structural Stabilization of Formamidinium Lead Iodide Perovskite by Using Embedded Quantum Dots
American Chemical Society (2020-01-6)The approaches to stabilize the perovskite structure of formamidinium lead iodide (FAPI) commonly result in a blue shift of the band gap, which limits the maximum photoconversion efficiency. Here, we report the use of PbS ... -
Chemical Inductor
American Chemical Society (2022-03-22)A multitude of chemical, biological, and material systems present an inductive behavior that is not electromagnetic in origin. Here, it is termed a chemical inductor. We show that the structure of the chemical inductor ... -
Chemically Fueled Autonomous Sol→Gel→Sol→Gel→Sol Transitions
Wiley (2023-06-05)Complex non-equilibrium phase behaviors are a hallmark of natural self-assembling systems. Here we show how intricate phase transitions can be achieved through a chemically fueled reaction cycle to yield autonomous ... -
Chemically Tunable Formation of Different Discrete, Oligomeric, and Polymeric Self‐Assembled Structures from Digold Metallotweezers
(2018)Digold metallotweezers whose complex supramolecular landscape is controlled by adding a series of metal cations are described. The metallotweezers have a strong tendency to form interesting supramolecular structures on ... -
Chemistry in light-induced 3D printing
Springer (2023-01-21)In the last few years, 3D printing has evolved from its original niche applications, such as rapid prototyping and hobbyists, towards many applications in industry, research and everyday life. This involved an evolution ... -
Chromium doped copper vanadate photoanodes for water splitting
Elsevier (2017-07-15)Solar hydrogen obtained from photoelectrochemical water splitting offers a versatile approach towards the substitution of fossil fuels by decentralized and sustainable resources, like water and sun. In the present study ... -
Clippane: A Mechanically Interlocked Molecule (MIM) Based on Molecular Tweezers
Wiley (2022-01-10)In this study we report the preparation of a new mechanically interlocked molecule formed by the self-aggregation of two metallotweezers composed by two pyrene-imidazolylidene gold(I) arms and a pyridine-centered pentacyclic ... -
Cobalt Hexacyanoferrate as a Selective and High Current Density Formate Oxidation Electrocatalyst
American Chemical Society (2020-09-28)Herein we report the selectivity, stability, and electrochemical characterization of cobalt hexacyanoferrate, the Co–Fe Prussian Blue derivative (CoFePB), as a formate/formic acid oxidation electrocatalyst in aqueous media. ... -
Cobalt Hexacyanoferrate on BiVO4 Photoanodes for Robust Water Splitting
(2017-11-01)The efficient integration of photoactive and catalytic materials is key to promoting photoelectrochemical water splitting as a sustainable energy technology built on solar power. Here, we report highly stable water splitting ... -
Combined Theoretical and Experimental Study to Unravel the Differences in Promiscuous Amidase Activity of Two Nonhomologous Enzymes
American Chemical Society (2021-07-16)Convergent evolution has resulted in nonhomologous enzymes that contain similar active sites that catalyze the same primary and secondary reactions. Comparing how these enzymes achieve their reaction promiscuity can yield ... -
Combining Modulated Techniques for the Analysis of Photosensitive Devices
Wiley-VCH GmbH (2021-09-03)Small-perturbation techniques such as impedance spectroscopy (IS), inten-sity-modulated photocurrent spectroscopy (IMPS), and intensity-modulated photovoltage spectroscopy (IMVS) are useful tools to characterize and model ... -
Combining Perovskites and Quantum Dots: Synthesis, Characterization, and Applications in Solar Cells, LEDs, and Photodetectors
Wiley (2022)Metal halide perovskites having high defect tolerance, high absorption characteristics, and high carrier mobility demonstrate great promise as potential light harvesters in photovoltaics and optoelectronics and have ... -
Combining Satellite Images and Cadastral Information for Outdoor Autonomous Mapping and Navigation: A Proof-of-Concept Study in Citric Groves
(2019-09-11)The development of robotic applications for agricultural environments has several problems which are not present in the robotic systems used for indoor environments. Some of these problems can be solved with an efficient ...