Changes from Bulk to Surface Recombination Mechanisms between Pristine and Cycled Perovskite Solar Cells
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Otros documentos de la autoría: Correa-Baena, Juan-Pablo; Turren Cruz, Silver Hamill; Tress, Wolfgang; Hagfeldt, Anders; Aranda Alonso, Clara; Shooshtari, Leyla; Bisquert, Juan; Guerrero, Antonio
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http://dx.doi.org/10.1021/acsenergylett.7b00059 |
Metadatos
Título
Changes from Bulk to Surface Recombination Mechanisms between Pristine and Cycled Perovskite Solar CellsAutoría
Fecha de publicación
2017Editor
American Chemical SocietyISSN
2380-8195Cita bibliográfica
CORREA-BAENA, Juan-Pablo, et al. Changes from Bulk to Surface Recombination Mechanisms between Pristine and Cycled Perovskite Solar Cells. ACS Energy Letters, 2017, vol. 2, no 3, p. 681-688.Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
http://pubs.acs.org/doi/abs/10.1021/acsenergylett.7b00059Versión
info:eu-repo/semantics/publishedVersionPalabras clave / Materias
Resumen
Several aspects on the photophysical characterization of lead halide hybrid organic–inorganic perovskite solar cells remain unsolved. It has been observed that ionic transport and polarization of the interfaces cause ... [+]
Several aspects on the photophysical characterization of lead halide hybrid organic–inorganic perovskite solar cells remain unsolved. It has been observed that ionic transport and polarization of the interfaces cause very slow changes that interfere with transient measurements with effects that cannot be separated from recombination kinetics. Here we establish a protocol of initial measurement of the solar cell that provides information on recombination characteristics prior to applying any voltage cycling. The photovoltaic device is measured by several methods (photovoltage versus light intensity, open-circuit voltage decay, and impedance spectroscopy) while minimizing the exposure to external voltage stimulus to avoid ionic migration to the contacts. Results are independently confirmed by the analysis of samples with interdigitated electrodes. We show that the high-efficiency perovskite solar cells behave very closely to a bulk recombination ideal photovoltaic model. However, when voltage is scanned to determine current density–voltage curves and impedance spectroscopy at fixed illumination intensity, the cell undergoes significant changes, which we attribute to a dominance of recombination at contacts that have been modified by ionic polarization. Our method provides an effective approach for determining quantitatively the rather significant changes that occur to perovskite solar cells during standard measurements, such as current–voltage curves. [-]
Publicado en
ACS Energy Letters, 2017, vol. 2, no 3, p. 681-688Proyecto de investigación
MINECO / MAT2016-76892-C3-1-R; Generalitat Valenciana / PROMETEOII/2014/020; Spanish Ministerio de Economia y Competitividad / RYC-2014-16809Derechos de acceso
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