Polymorphism-Triggered Reversible Thermochromic Fluorescence of a simple 1,8-Naphthyridine
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Scholar |
Otros documentos de la autoría: Fernández Mato, Antonio; García, Marcos D.; Peinador, Carlos; Quintela, José M.; Sánchez Andújar, Manuel; Pato Doldán, Breogán; Señarís-Rodríguez, M. A.; Tordera, Daniel; Bolink, Henk J.
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http://dx.doi.org/10.1021/cg301656x |
Metadatos
Título
Polymorphism-Triggered Reversible Thermochromic Fluorescence of a simple 1,8-NaphthyridineAutoría
Fecha de publicación
2013-01-04Editor
ACS PublicationsISSN
1528-7483; 1528-7505Cita bibliográfica
FERNÁNDEZ-MATO, Antonio, et al. Polymorphism-Triggered Reversible Thermochromic Fluorescence of a Simple 1, 8-Naphthyridine. Crystal Growth & Design, 2013, vol. 13, no 2, p. 460-464Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
http://pubs.acs.org/doi/abs/10.1021/cg301656xPalabras clave / Materias
Resumen
The fluorescent behavior in the solid state of a naphthyridine-based donor–acceptor heterocycle is presented. Synthesized as a crystalline blue-emissive solid (Pbca), the compound can easily be transformed in its P21/c ... [+]
The fluorescent behavior in the solid state of a naphthyridine-based donor–acceptor heterocycle is presented. Synthesized as a crystalline blue-emissive solid (Pbca), the compound can easily be transformed in its P21/c polymorphic form by heating. The latter material shows blue to cyan emission switching triggered by a reversible thermally induced phase transformation. This fact, the reversible acidochromism, and the strong anisotropic fluorescence of the compound in the solid state, account for the potential of 1,8-naphthyridines as simple and highly tunable organic compounds in materials science. [-]
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Crystal Growth & Design, 2013, vol. 13, no 2Derechos de acceso
Copyright © 2013 American Chemical Society
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