Rhodium–NHC complexes mediate diboration versus dehydrogenative borylation of cyclic olefins: a theoretical explanation†
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Other documents of the author: Pubill Ulldemolins, Cristina; Poyatos, Macarena; Bo, Carles; Fernández, Elena
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Title
Rhodium–NHC complexes mediate diboration versus dehydrogenative borylation of cyclic olefins: a theoretical explanation†Date
2013Publisher
Royal Society of ChemistryType
info:eu-repo/semantics/articlePublisher version
http://bs8lz6ys5q.search.serialssolutions.com/?ctx_ver=Z39.88-2004&ctx_enc=info% ...Subject
Abstract
In rhodium catalysed borylation of cyclic olefins, the synergy between bidentate NHC ligands, that
modify cationic Rh(I) species, and the use of non-polar solvents, such as cyclohexane, is the key factor to
favour ... [+]
In rhodium catalysed borylation of cyclic olefins, the synergy between bidentate NHC ligands, that
modify cationic Rh(I) species, and the use of non-polar solvents, such as cyclohexane, is the key factor to
favour a less energetically demanding route towards the formation of diborated products versus allyl
boronate esters. [-]
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Dalton Transactions. 2013, 42Rights
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