Rhodium–NHC complexes mediate diboration versus dehydrogenative borylation of cyclic olefins: a theoretical explanation†

Pubill Ulldemolins, Cristina; Poyatos, Macarena; Bo, Carles; Fernández, Elena

dc.contributor.author	Pubill Ulldemolins, Cristina
dc.contributor.author	Poyatos, Macarena
dc.contributor.author	Bo, Carles
dc.contributor.author	Fernández, Elena
dc.date.accessioned	2014-04-04T13:41:58Z
dc.date.available	2014-04-04T13:41:58Z
dc.date.issued	2013
dc.identifier.uri	http://hdl.handle.net/10234/89436
dc.description.abstract	In rhodium catalysed borylation of cyclic olefins, the synergy between bidentate NHC ligands, that modify cationic Rh(I) species, and the use of non-polar solvents, such as cyclohexane, is the key factor to favour a less energetically demanding route towards the formation of diborated products versus allyl boronate esters.	ca_CA
dc.format.extent	6 p.	ca_CA
dc.format.mimetype	application/pdf	ca_CA
dc.language.iso	eng	ca_CA
dc.publisher	Royal Society of Chemistry	ca_CA
dc.relation.isPartOf	Dalton Transactions. 2013, 42	ca_CA
dc.rights	© Royal Society of Chemistry 2014	ca_CA
dc.rights.uri	http://rightsstatements.org/vocab/InC/1.0/	*
dc.subject	Rhodium–NHC	ca_CA
dc.title	Rhodium–NHC complexes mediate diboration versus dehydrogenative borylation of cyclic olefins: a theoretical explanation†	ca_CA
dc.type	info:eu-repo/semantics/article	ca_CA
dc.identifier.doi	http://dx.doi.org/10.1039/c2dt31659e
dc.rights.accessRights	info:eu-repo/semantics/restrictedAccess	ca_CA
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