Rhodium–NHC complexes mediate diboration versus dehydrogenative borylation of cyclic olefins: a theoretical explanation†
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Altres documents de l'autoria: Pubill Ulldemolins, Cristina; Poyatos, Macarena; Bo, Carles; Fernández, Elena
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Títol
Rhodium–NHC complexes mediate diboration versus dehydrogenative borylation of cyclic olefins: a theoretical explanation†Data de publicació
2013Editor
Royal Society of ChemistryTipus de document
info:eu-repo/semantics/articleVersió de l'editorial
http://bs8lz6ys5q.search.serialssolutions.com/?ctx_ver=Z39.88-2004&ctx_enc=info% ...Paraules clau / Matèries
Resum
In rhodium catalysed borylation of cyclic olefins, the synergy between bidentate NHC ligands, that
modify cationic Rh(I) species, and the use of non-polar solvents, such as cyclohexane, is the key factor to
favour ... [+]
In rhodium catalysed borylation of cyclic olefins, the synergy between bidentate NHC ligands, that
modify cationic Rh(I) species, and the use of non-polar solvents, such as cyclohexane, is the key factor to
favour a less energetically demanding route towards the formation of diborated products versus allyl
boronate esters. [-]
Publicat a
Dalton Transactions. 2013, 42Drets d'accés
© Royal Society of Chemistry 2014
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