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Study of the Stereoselectivity of the Nucleophilic Epoxidation of 3-Hydroxy-2- methylene Esters

dc.contributor.authorLatorre, Antonio
dc.contributor.authorSáez Cases, José Antonio
dc.contributor.authorRodríguez, Santiago
dc.contributor.authorGonzález, Florenci
dc.date.accessioned2014-03-31T07:11:48Z
dc.date.available2014-03-31T07:11:48Z
dc.date.issued2013-01
dc.identifier.citationLATORRE, Antonio, et al. Study of the stereoselectivity of the nucleophilic epoxidation of 3-hydroxy-2-methylene esters. Tetrahedron, 2014, 70.1: 97-102.ca_CA
dc.identifier.urihttp://hdl.handle.net/10234/88869
dc.description.abstractThe diastereoselectivity of the nucleophilic epoxidation of 3-hydroxy-2-methylene esters has been studied. The 3-hydroxy-2-methylene esters were obtained through a Morita–Baylis–Hillman reaction. The resulting epoxyesters were treated with thiophenol for transformation into 2,3-dihydroxy-2-((phenylthio)methyl), which upon treatment with triphosgene afforded the corresponding cyclic carbonates.ca_CA
dc.format.extent5 p.ca_CA
dc.format.mimetypeapplication/pdfca_CA
dc.language.isoengca_CA
dc.publisherElsevierca_CA
dc.relation.isPartOfTetrahedron Volume 70, Issue 1, 7 January 2014ca_CA
dc.rightsCopyright © 2014 Elsevier B.V.ca_CA
dc.rights.urihttp://rightsstatements.org/vocab/InC/1.0/*
dc.subjectchemical reactionca_CA
dc.subjectepoxidationca_CA
dc.subjectMorita Baylis Hillman reactionca_CA
dc.subjectnucleophilicityca_CA
dc.subjectstereochemistryca_CA
dc.subjectcarbonic acid derivativeca_CA
dc.subjectester derivativeca_CA
dc.subjectthiophenol derivativeca_CA
dc.titleStudy of the Stereoselectivity of the Nucleophilic Epoxidation of 3-Hydroxy-2- methylene Estersca_CA
dc.typeinfo:eu-repo/semantics/articleca_CA
dc.identifier.doihttp://dx.doi.org/10.1016/j.tet.2013.11.014
dc.rights.accessRightsinfo:eu-repo/semantics/openAccessca_CA
dc.relation.publisherVersionhttp://www.sciencedirect.com/science/article/pii/S004040201301702X
dc.type.versioninfo:eu-repo/semantics/acceptedVersion


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