Listar QUIO_Articles por autoría "1a53fde5-46dc-4ef0-a633-82f87f072aa6"
Mostrando ítems 61-80 de 80
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Sponge-Like Ionic Liquids a new platform for green biocatalytic chemical processes
Lozano, Pedro; Bernal, Juana M.; Garcia-Verdugo, Eduardo; Sánchez Gómez, Gregorio; Vaultier, Michel; Burguete, M. Isabel; Luis, Santiago V. Royal Society of Chemistry (2015)To build a green chemical industry it is necessary to develop integrated processes of selective transformation and separation, able to directly provide pure products, including the reuse of all the elements of the reaction ... -
Stereoselective chemoenzymatic synthesis of enantiopure 2-(1H-imidazol-yl)cycloalkanols under continuous flow conditions
Burguete, M. Isabel; Luis, Santiago V.; Garcia-Verdugo, Eduardo; Porcar Garcia, Raul; Sans, Victor; Ríos-Lombardía, Nicolás; Gotor Fernández, Vicente; Gotor Fernández, Vicente American Chemical Society (2012-07)The development of continuous flow processes for the synthesis of chiral enantiopure 1-(2-hydroxycycloalkyl)imidazoles is reported. For the ring-opening reaction microwave batch processes and continuous flow reactions have ... -
Supercritical Synthesis of Biodiesel
Bernal, Juana M.; Lozano, Pedro; Garcia-Verdugo, Eduardo; Burguete, M. Isabel; Sánchez Gómez, Gregorio; López López, Gregorio; Pucheault, Mathieu; Vaultier, Michel; Luis, Santiago V. MDPI Publishing (2012)The synthesis of biodiesel fuel from lipids (vegetable oils and animal fats) has gained in importance as a possible source of renewable non-fossil energy in an attempt to reduce our dependence on petroleum-based fuels. The ... -
Supported ionic liquid-like phases as efficient solid ionic solvents for the immobilisation of alcohol dehydrogenases towards the development of stereoselective bioreductions
Porcar Garcia, Raul; Lavandera, Ivan; Lozano, Pedro; Altava, Belen; Luis, Santiago V.; Gotor Fernández, Vicente; Garcia-Verdugo, Eduardo Royal Society of Chemistry (2021)PORCAR, Raul, et al. Supported Ionic Liquid-Like Phases as efficient solid ionic solvent for the immobilisation of alcohol dehydrogenases towards the development of stereoselective bioreductions. Green Chemistry, 2021. -
Supported ionic liquid-like phases as organocatalysts for the solvent-free cyanosilylation of carbonyl compounds: from batch to continuous flow process
Martín, Sergio; Porcar Garcia, Raul; Peris, Edgar; Burguete, M. Isabel; Garcia-Verdugo, Eduardo; Luis, Santiago V. Royal Society of Chemistry (2014)Supported ionic liquid-like phases (SILLPs) are able to efficiently catalyse the cyanosilylation of carbonyl compounds using trimethylsilyl cyanide under solvent-free conditions. These organic catalysts were efficient for ... -
Supported Ionic Liquid‐Like Phases (SILLPs) as Immobilised Catalysts for the Multistep and Multicatalytic Continuous Flow Synthesis of Chiral Cyanohydrins
Peris, Edgar; Porcar Garcia, Raul; Burguete, M. Isabel; Garcia-Verdugo, Eduardo; Luis, Santiago V. (2019)Supported Ionic Liquid‐Like Phases have been found to be efficient organocatalysts for the synthesis of cyanohydrin esters under solvent‐free conditions by an “electrophile‐nucleophile dual activation” based on hydrogen ... -
Supported N-heterocyclic carbene rhodium complexes as highly selective hydroformylation catalysts
Gil, W.; Boczon, K.; Trzeciak, Anna M.; Ziolkowski, Józef J.; Garcia-Verdugo, Eduardo; Luis, Santiago V.; Sans, Victor Elsevier (2009)New supported rhodium(I) catalyst precursors were obtained in reaction of [Rh(OMe)(cod)]<sub>2</sub> with polymeric monoliths containing methyl-imidazolium moieties and applied in 1-hexene hydroformylation at 10 atm of ... -
Supramolecular Interactions Based on Ionic Liquids for Tuning of the Catalytic Efficiency of (L)-Proline
Porcar Garcia, Raul; Burguete, M. Isabel; Lozano, Pedro; Garcia-Verdugo, Eduardo; Luis, Santiago V. American Chemical Society (2016-09)Noncovalent intermolecular interactions between (l)-proline and ionic liquids (ILs) are key to explain the different catalytic efficiencies observed for this organocatalyst in the aldol reaction carried out in ILs or in ... -
Synergy between supported ionic liquid-like phases and immobilized palladium N-heterocyclic carbene–phosphine complexes for the Negishi reaction under flow conditions
Peris, Edgar; Porcar Garcia, Raul; Maciá, María; Alcázar, Jesús; Garcia-Verdugo, Eduardo; Luis, Santiago V. Beilstein-Institut (2020)The combination of supported ionic liquids and immobilized NHC–Pd–RuPhos led to active and more stable systems for the Negishi reaction under continuous flow conditions than those solely based on NHC–Pd–RuPhos. The fine ... -
Synthesis and characterization of the conductivity and polarization processes in supported ionic liquid-like phases (SILLPs)
Compañ, Vicente; Mollá, Sergio; Garcia-Verdugo, Eduardo; Luis, Santiago V.; Burguete, M. Isabel Elsevier (2012)Different crosslinked polystyrene resins containing ionic liquid fragments covalently attached (supported ionic liquid-like phases: SILLPs) have been prepared and their conductivity has been studied by means of dielectric ... -
Synthesis of chiral room temperature ionic liquids from amino acids – application in chiral molecular recognition
González, Laura; Altava, Belen; Bolte, Michael; Burguete, M. Isabel; Garcia-Verdugo, Eduardo; Luis, Santiago V. Wiley-VCH Verlag (2012)A series of structurally new room temperature chiral ionic liquids based on an imidazolium group and derived from natural amino acids have been synthesized and studied as chiral shift agents for the chiral discrimination ... -
The key role of pretreatment for the one-step and multi-step conversions of European lignocellulosic materials into furan compounds
Kammoun, Maroua; Margellou, Antigoni; Toteva, Vesislava; aladjadjiyan, anna; Fernandes de Sousa, Andreia; Luis, Santiago V.; Garcia-Verdugo, Eduardo; Triantafyllidis, Konstantinos; Richel, Aurore Royal Society of Chemistry (2023)Nowadays, an increased interest from the chemical industry towards the furanic compounds production, renewable molecules alternatives to fossil molecules, which can be transformed into a wide range of chemicals and ... -
Tools and new metric (Macrocyclization Environmental Impact - MEI) to tackle the sustainability of macrocyclization reactions
Esteve Franch, Ferran; Altava, Belen; Luis, Santiago V.; Garcia-Verdugo, Eduardo Elsevier (2023-10-06)Albeit the numerous scientific advantages provided by macrocyclic compounds, there is still a significant gap between the “proof of concept” research and their application. This is a direct consequence of the challenging ... -
Towards highly efficient continuous-flow catalytic carbon dioxide cycloadditions with additively manufactured reactors
Valverde Barquero, David; Porcar Garcia, Raul; Zanatta, Marcileia; Alcalde, Sergio; Altava, Belen; Sans, Victor; Garcia-Verdugo, Eduardo The Royal Society of Chemistry (2022-03-22)Developing efficient and sustainable methodologies to transform CO2 into added-value chemicals is an important strategy for decarbonization in the chemical industry. Here, a new multi-scale approach for the cycloaddition ... -
Tripodal amphiphilic pseudopeptidic nanovesicles as p-coumaric acid delivery systems for brain cancer cells
Lotfallah, Ahmed H.; Andreu Olaria, José Juan; Hathout, R.M.; Kassem, D.H.; Ibrahim, S.S.; Altava, Belen; Garcia-Verdugo, Eduardo; Luis, Santiago V. Elsevier (2022-11)Nanovesicles based on tripodal amphiphilic pseudopeptides are prepared as carriers for p-coumaric acid (p-CA) delivery. Loaded nanovesicles are obtained by both thin film hydration and ethanol injection methods with ... -
Tuneable 3D printed bioreactors for transaminations under continuous-flow
Peris, Edgar; Okafor, Obinna; Kulcinskaja, Evelina; Goodridge, Ruth; Luis, Santiago V.; Garcia-Verdugo, Eduardo; O'Reilly, Elaine; Sans, Victor Royal Society of Chemistry (2017-11-21)A method to efficiently immobilize enzymes on 3D printed continuous- fl ow devices is presented. Application of these chemically modi fi ed devices enables rapid screening of immobilization mechanisms and ... -
Tuning lipase B from Candida antarctica C–C bond promiscuous activity by immobilization on poly-styrene-divinylbenzene beads
Izquierdo Henríquez, Diana F.; Barbosa, Oveimar; Burguete, M. Isabel; Lozano, Pedro; Luis, Santiago V.; Fernandez Lafuente, Roberto; Garcia-Verdugo, Eduardo Royal Society of Chemistry (2013-12)Lipase B from Candida antarctica (CALB) is able to catalyze C–C bond formation. After immobilization onto a hydrophobic PS-DVB support, the activity increases when compared to that of the soluble or tan – the commercially ... -
Tuning Ni-Pyrazolate Frameworks by Post-Synthetic Fe-Incorporation for Oxidase-Mimicking H2O2 Activation
Martín, Nuria; Cirujano, Francisco; Garcia-Verdugo, Eduardo; Llorca, Jordi; del Río Nieto, Enrique; Jiménez Morales, Ignacio; Bogeat Barroso, Adrián; López-Maya, Elena; Garcia Alvarez, Mayra Wiley (2023-10-04)The introduction of iron ionic sites by metal exchange of defective homometallic nickel pyrazolate frameworks generates non-precious, Earth-abundant, first-row heterometallic Fe/Ni-pyrazolate frameworks. The Fe incorporation ... -
Tuning the Catalytic Efficiency of Palladium Supported Complexes (Pd-NHC-SILLPs): The Cooperative Effect of the Ionic Liquid-Like Groups
Sans, Victor; Gelat, Fabien; Burguete, M. Isabel; Garcia-Verdugo, Eduardo; Luis, Santiago V. WILEY-VCH Verlag (2012)Gel-type Supported Ionic Liquid-like Phases (g-SILLPs) have been employed as medium for the preparation of Palladium carbene (Pd-NHC) complexes. These supported complexes onto ionic liquid-like phases were employed as ... -
Unravelling the Supramolecular Driving Forces in the Formation of CO2-Responsive Pseudopeptidic Low-Molecular-Weight Hydrogelators
Esteve Franch, Ferran; Villanueva Antoli, Alexis; Altava, Belen; Garcia-Verdugo, Eduardo; Luis, Santiago V. MDPI (2022): A new family of C2 -symmetric pseudopeptides with a high functional density for supramolecular interactions has been synthetized through the attachment of four amino acid subunits to a diamino aliphatic spacer. The ...