Listar QUIO_Articles por autoría "197450e8-f78f-445e-8afe-1bd4a8b93e02"
Mostrando ítems 1-13 de 13
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Base Supported Ionic Liquid-Like Phases as catalysts for the Batch and Continuous-Flow Henry Reaction
Garcia-Verdugo, Eduardo; Erythropel, Hanno; Burguete, M. Isabel; Sans, Victor; Luis, Santiago V. Royal Society of Chemistry (2008)New solid basic catalysts immobilised onto supported ionic liquid-like phases have been prepared, having suitable mechanical stability for their use for the continuous-flow Henry reaction -
Development of efficient processes under flow conditions based on catalysts immobilized onto monolithic supported ionic liquid-like phases
Burguete, M. Isabel; Garcia-Verdugo, Eduardo; Karbass, Naima; Luis, Santiago V.; Sans, Victor; Sokolova, Maia International Union of Pure and Applied Chemistry (2009)The introduction of imidazolium subunits into polystyrene-divinylbenzene (PS-DVB) polymers enables the preparation of a variety of catalytic systems. Those include the stabilization of catalytically active Pd nanoparticles ... -
Direct Air Capture and Integrated Conversion of Carbon Dioxide into Cyclic Carbonates with Basic Organic Salts
Zanatta, Marcileia; Garcia-Verdugo, Eduardo; Sans, Victor American Chemical Society (2023-07-03)Direct air capture and integrated conversion is a very attractive strategy to reduce CO2 concentration in the atmosphere. However, the existing capturing processes are technologically challenging due to the costs of the ... -
On the role of multifunctional ionic liquids for the oxidative carboxylation of olefins with carbon dioxide
Podrojková, Natália; Orinak, Andrej; Garcia-Verdugo, Eduardo; Sans, Victor; Zanatta, Marcileia Elsevier (2023-03-23)Ionic liquids (ILs) are catalysts with profound effects on the activity and selectivity for the transformation of CO2. In particular, highly functionalisable and immobilisable imidazolium based ILs (ImILs) activate CO2 ... -
Pd catalysts immobilized onto gel-supported ionic liquid-like phases (g-SILLPs): A remarkable effect of the nature of the support
Burguete, M. Isabel; Garcia-Verdugo, Eduardo; García Villar, Ignacio; Gelat, Fabien; Licence, Peter; Luis, Santiago V.; Sans, Victor Elsevier (2010)New polymeric materials containing functional sites analogous to ionic liquids have been synthesized. Those materials are a supported reservoir for the active Pd species. Their catalytic activity has been evaluated for the ... -
Polymer-supported ionic-liquid-like phases (SILLPs): transferring ionic liquid properties to polymeric matrices
Sans, Victor; Karbass, Naima; Burguete, M. Isabel; Compañ, Vicente; Garcia-Verdugo, Eduardo; Luis, Santiago V.; Pawlak, Milena Wiley (2011-01-12)The physico-chemical properties of polymers with ionic-liquid-like moieties covalently bound to their surfaces (SILLPs) have been studied by thermal and spectroscopic techniques, as well as by direct impedance and dielectric ... -
Polymer-supported Pd–NHC complexes: Strategies for the development of multifunctional systems
Sans, Victor; Gelat, Fabien; Burguete, M. Isabel; Garcia-Verdugo, Eduardo; Luis, Santiago V. Elsevier (2012-11)Different strategies to introduce multiple ionic liquid-like functionalities in PS–DVB based polymers in an easy and reproducible way are reported. A basic common structural element has been, in all cases, the presence of ... -
Residence time distribution, a simple tool to understand the behaviour of polymeric mini-flow reactors
Burguete, M. Isabel; Garcia-Verdugo, Eduardo; Luis, Santiago V.; Sans, Victor; Karbass, Naima Royal Society of Chemistry (2012-09)A simple method for the determination of the residence time distribution (RTD) of different polymer-based mini-flow reactors has been developed. The flow patterns have been adjusted employing the axial dispersion model, ... -
Stereoselective chemoenzymatic synthesis of enantiopure 2-(1H-imidazol-yl)cycloalkanols under continuous flow conditions
Burguete, M. Isabel; Luis, Santiago V.; Garcia-Verdugo, Eduardo; Porcar Garcia, Raul; Sans, Victor; Ríos-Lombardía, Nicolás; Gotor Fernández, Vicente; Gotor Fernández, Vicente American Chemical Society (2012-07)The development of continuous flow processes for the synthesis of chiral enantiopure 1-(2-hydroxycycloalkyl)imidazoles is reported. For the ring-opening reaction microwave batch processes and continuous flow reactions have ... -
Supported N-heterocyclic carbene rhodium complexes as highly selective hydroformylation catalysts
Gil, W.; Boczon, K.; Trzeciak, Anna M.; Ziolkowski, Józef J.; Garcia-Verdugo, Eduardo; Luis, Santiago V.; Sans, Victor Elsevier (2009)New supported rhodium(I) catalyst precursors were obtained in reaction of [Rh(OMe)(cod)]<sub>2</sub> with polymeric monoliths containing methyl-imidazolium moieties and applied in 1-hexene hydroformylation at 10 atm of ... -
Towards highly efficient continuous-flow catalytic carbon dioxide cycloadditions with additively manufactured reactors
Valverde Barquero, David; Porcar Garcia, Raul; Zanatta, Marcileia; Alcalde, Sergio; Altava, Belen; Sans, Victor; Garcia-Verdugo, Eduardo The Royal Society of Chemistry (2022-03-22)Developing efficient and sustainable methodologies to transform CO2 into added-value chemicals is an important strategy for decarbonization in the chemical industry. Here, a new multi-scale approach for the cycloaddition ... -
Tuneable 3D printed bioreactors for transaminations under continuous-flow
Peris, Edgar; Okafor, Obinna; Kulcinskaja, Evelina; Goodridge, Ruth; Luis, Santiago V.; Garcia-Verdugo, Eduardo; O'Reilly, Elaine; Sans, Victor Royal Society of Chemistry (2017-11-21)A method to efficiently immobilize enzymes on 3D printed continuous- fl ow devices is presented. Application of these chemically modi fi ed devices enables rapid screening of immobilization mechanisms and ... -
Tuning the Catalytic Efficiency of Palladium Supported Complexes (Pd-NHC-SILLPs): The Cooperative Effect of the Ionic Liquid-Like Groups
Sans, Victor; Gelat, Fabien; Burguete, M. Isabel; Garcia-Verdugo, Eduardo; Luis, Santiago V. WILEY-VCH Verlag (2012)Gel-type Supported Ionic Liquid-like Phases (g-SILLPs) have been employed as medium for the preparation of Palladium carbene (Pd-NHC) complexes. These supported complexes onto ionic liquid-like phases were employed as ...