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Rhodium–NHC complexes mediate diboration versus dehydrogenative borylation of cyclic olefins: a theoretical explanation†
(Royal Society of Chemistry, 2013)
In rhodium catalysed borylation of cyclic olefins, the synergy between bidentate NHC ligands, that
modify cationic Rh(I) species, and the use of non-polar solvents, such as cyclohexane, is the key factor to
favour a less ...
C2 symmetrical nickel complexes derived from α-amino amides as efficient catalysts for the enantioselective addition of dialkylzinc reagents to aldehydes
(Elsevier, 2013-01)
A series of C2 symmetrical 1:2 Ni:L complexes derived from α-amino amides were studied for the enantioselective addition of dialkylzinc reagents to aldehydes. Different structural elements on the ligands seem to play an ...
Interplay of Molecular Hydrogelators and SDS Affords Responsive Soft Matter Systems with Tunable Properties
(American Chemical Society, 2013)
The gelation efficiency of low molecular weight bolaamphiphilic hydrogelators 1 and 2 is influenced by the presence of SDS micelles. Similarly, the critical micellar concentration value of SDS is reduced in the presence ...
Triphenylene-Based Tris(N-Heterocyclic Carbene) Ligand: Unexpected Catalytic Benefits
(Wiley, 2013-07-01)
Triple play: A novel triphenylene-based tris(N-heterocyclic carbene) ligand with D3h symmetry and a highly π-delocalized system has been prepared and coordinated to palladium and gold (see figure). The catalytic activities ...
Substrate selective catalytic molecular hydrogels: the role of the hydrophobic effect
(Royal Society of Chemistry, 2013-09-17)
A catalytic hydrogel is reported for the substrate selective direct aldol reaction of aliphatic ketones based on their hydrophobicity and on the emergence of catalytic activity only after self-assembly of the catalyst.
A photoinduced electron transfer-based nanoprobe as a marker of acidic organelles in mammalian cells
(Springer, 2013-07)
Photoinduced electron transfer (PET)-based molecular probes have been successfully used for the intracelular imaging of the pH of acidic organelles. In this study, we describe the synthesis and characterization of a novel ...
The atypical dopamine transport inhibitor, JHW 007, prevents amphetamine-induced sensitization and synaptic reorganization within the nucleus accumbens
(Elsevier, 2013)
Benztropine (BZT) analogs, a family of agents with high affinity for the dopamine transporter have been postulated as potential treatments in stimulant abuse due to their ability to attenuate a wide range of effects evoked ...
Stereoselective synthesis of a C1-C18 fragment of amphidinolides G and H
(Elsevier, 2013-04)
A stereoselective synthesis of a C1–C18 segment of the structure of the cytotoxic macrolides amphidinolides G and H is reported. The target compound was retrosynthetically disconnected into three fragments. In the synthetic ...
Voltage-Dependent Bulk Resistivity of SrTiO3:Mg Ceramics
(John Wiley & Sons, 2014)
Single phase ceramics of composition Sr(Ti1–xMgx)O3–x: 0 ≤ x ≤ 0.01 were prepared by sol–gel synthesis and characterized by X-ray diffraction, scanning electron microscopy, impedance spectroscopy, and current–voltage ...
Synthesis of new fluorescent pyrylium dyes and study of their interaction with N-protected amino acids
(Royal Society of Chemistry, 2020)
Six new 6-styryl-2,4-diarylpyrylium salts have been synthesized and fully characterized by means of 1H/13C NMR, HRMS, UV-vis and Steady-State/Time-Resolved Fluorescence spectroscopies. This set of molecules is composed of ...