Regioselective ring opening and isomerization reactions of 3,4-epoxyesters catalyzed by boron trifluoride
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http://dx.doi.org/10.1021/ol201378w |
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Título
Regioselective ring opening and isomerization reactions of 3,4-epoxyesters catalyzed by boron trifluorideFecha de publicación
2011Editor
American Chemical SocietyISSN
1523-7060Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
http://pubs.acs.org/doi/full/10.1021/ol201378wPalabras clave / Materias
Resumen
Efficient ring opening of 3,4-epoxyesters with alcohols to produce 4-alkoxy-3-hydroxyesters and their isomerization into 4-ketoesters using boron trifluoride as the catalyst are presented. Both transformations are ... [+]
Efficient ring opening of 3,4-epoxyesters with alcohols to produce 4-alkoxy-3-hydroxyesters and their isomerization into 4-ketoesters using boron trifluoride as the catalyst are presented. Both transformations are simple and efficient methods for the synthesis of the above named synthetically useful compounds. [-]
Publicado en
Organic Letters (2011), vol. 13, no. 15, 3856–3859Derechos de acceso
© 2011 American Chemical Society
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