Regioselective ring opening and isomerization reactions of 3,4-epoxyesters catalyzed by boron trifluoride
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http://dx.doi.org/10.1021/ol201378w |
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Títol
Regioselective ring opening and isomerization reactions of 3,4-epoxyesters catalyzed by boron trifluorideData de publicació
2011Editor
American Chemical SocietyISSN
1523-7060Tipus de document
info:eu-repo/semantics/articleVersió de l'editorial
http://pubs.acs.org/doi/full/10.1021/ol201378wParaules clau / Matèries
Resum
Efficient ring opening of 3,4-epoxyesters with alcohols to produce 4-alkoxy-3-hydroxyesters and their isomerization into 4-ketoesters using boron trifluoride as the catalyst are presented. Both transformations are ... [+]
Efficient ring opening of 3,4-epoxyesters with alcohols to produce 4-alkoxy-3-hydroxyesters and their isomerization into 4-ketoesters using boron trifluoride as the catalyst are presented. Both transformations are simple and efficient methods for the synthesis of the above named synthetically useful compounds. [-]
Publicat a
Organic Letters (2011), vol. 13, no. 15, 3856–3859Drets d'accés
© 2011 American Chemical Society
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