General and selective iron-catalyzed transfer hydrogenation of nitroarenes without base
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http://dx.doi.org/10.1021/ja2061038 |
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Título
General and selective iron-catalyzed transfer hydrogenation of nitroarenes without baseAutoría
Fecha de publicación
2011-08Editor
American Chemical SocietyISSN
0002-7863Cita bibliográfica
Journal of the American Chemical Society (August 2011), vol. 133, no. 32, 12875–12879Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
http://pubs.acs.org/doi/pdfplus/10.1021/ja2061038Versión
info:eu-repo/semantics/publishedVersionPalabras clave / Materias
Resumen
The first well-defined iron-based catalyst system for the
reduction of nitroarenes to anilines has been developed applying formic
acid as reducing agent. A broad range of substrates including other reducible
func ... [+]
The first well-defined iron-based catalyst system for the
reduction of nitroarenes to anilines has been developed applying formic
acid as reducing agent. A broad range of substrates including other reducible
functional groups were converted to the corresponding anilines in good to
excellent yields at mild conditions. Notably, the process constitutes a rare
example of base-free transfer hydrogenations. [-]
Derechos de acceso
© 2011 American Chemical Society
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