General and selective iron-catalyzed transfer hydrogenation of nitroarenes without base
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comunitat-uji-handle2:10234/7013
comunitat-uji-handle3:10234/8638
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http://dx.doi.org/10.1021/ja2061038 |
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Title
General and selective iron-catalyzed transfer hydrogenation of nitroarenes without baseAuthor (s)
Date
2011-08Publisher
American Chemical SocietyISSN
0002-7863Bibliographic citation
Journal of the American Chemical Society (August 2011), vol. 133, no. 32, 12875–12879Type
info:eu-repo/semantics/articlePublisher version
http://pubs.acs.org/doi/pdfplus/10.1021/ja2061038Version
info:eu-repo/semantics/publishedVersionSubject
Abstract
The first well-defined iron-based catalyst system for the
reduction of nitroarenes to anilines has been developed applying formic
acid as reducing agent. A broad range of substrates including other reducible
func ... [+]
The first well-defined iron-based catalyst system for the
reduction of nitroarenes to anilines has been developed applying formic
acid as reducing agent. A broad range of substrates including other reducible
functional groups were converted to the corresponding anilines in good to
excellent yields at mild conditions. Notably, the process constitutes a rare
example of base-free transfer hydrogenations. [-]
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© 2011 American Chemical Society
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- QFA_Articles [825]